308919
2-Bromo-4-fluoroanisole
96%
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About This Item
Linear Formula:
BrC6H3(F)OCH3
CAS Number:
Molecular Weight:
205.02
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
96%
Form:
liquid
InChI
1S/C7H6BrFO/c1-10-7-3-2-5(9)4-6(7)8/h2-4H,1H3
SMILES string
COc1ccc(F)cc1Br
InChI key
JIQXVIJARQLCOY-UHFFFAOYSA-N
assay
96%
form
liquid
refractive index
n20/D 1.545 (lit.)
bp
89 °C/1 mmHg (lit.)
density
1.581 g/mL at 25 °C (lit.)
functional group
bromo, fluoro
Quality Level
Application
2-Bromo-4-fluoroanisole was used in the synthesis of (5-fluoro-2-methoxyphenyl)methanol.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
208.4 °F - closed cup
flash_point_c
98 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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Catherine N Slattery et al.
The Journal of organic chemistry, 78(12), 5955-5963 (2013-05-31)
An efficient synthetic approach leading to introduction of the hydroxymethyl group to an aryl moiety via combination of the Bouveault formylation and hydride reduction has been optimized using a rational, mechanistic-based approach. This approach enabled telescoping of the two steps
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