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Merck
CN

309338

Nickel(II) perchlorate hexahydrate

Synonym(s):

Nickel(2+) diperchlorate hexahydrate

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About This Item

Linear Formula:
Ni(ClO4)2 · 6H2O
CAS Number:
13520-61-1
Molecular Weight:
365.69
NACRES:
NA.23
PubChem Substance ID:
24858728
UNSPSC Code:
12352302
EC Number:
237-124-1
MDL number:
MFCD00149804
Form:
crystalline

Key Documents

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InChI key

WHGYCGOFTBFDLW-UHFFFAOYSA-L

InChI

1S/2ClHO4.Ni.6H2O/c2*2-1(3,4)5;;;;;;;/h2*(H,2,3,4,5);;6*1H2/q;;+2;;;;;;/p-2

SMILES string

O.O.O.O.O.O.[Ni++].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O

form

crystalline

reaction suitability

core: nickel
reagent type: oxidant

concentration

15.3-17.0% Ni (EDTA titration)

mp

140 °C (lit.)

application(s)

battery precursors
catalysts
material synthesis precursor

Quality Level

100

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Related Categories

Application

Starting material for homometallic, trinuclear heteroscorpionate complexes applied in studies of electronic and magnetic properties.

signalword

Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A - Eye Dam. 1 - Muta. 2 - Ox. Sol. 3 - Repr. 1B - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT RE 1

Storage Class

5.1A - Strongly oxidizing hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
MKCX7094
MKCT2116
MKCV3399
MKCQ4591
MKCN5211

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Timothy C. Higgs et al.
Inorganic chemistry, 37(9), 2263-2272 (2001-10-24)
The mixed functionality pyrazole/phenol ligand (2-hydroxyphenyl)bis(pyrazolyl)methane, L1OH, has been used to prepare a series of linear trimetallic systems with the general structural motif [M(3)(L1O)(4)](2+), where M = Mn(2+), Co(2+), Ni(2+), Cu(2+), and Zn(2+). Each of these complexes has been structurally

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