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Merck
CN

318922

Ferroin indicator solution

0.1 wt. % in H2O

Synonym(s):

1,10-Phenanthroline iron(II) sulfate complex, o-Phenanthroline ferrous sulfate complex

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About This Item

Linear Formula:
[Fe(C12H8N2)3]SO4
CAS Number:
14634-91-4
Molecular Weight:
692.52
NACRES:
NA.47
PubChem Substance ID:
24858877
UNSPSC Code:
12171500
MDL number:
MFCD00036428

Key Documents

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Product Name

Ferroin indicator solution, 0.1 wt. % in H2O

InChI

1S/3C12H8N2.Fe.H2O4S/c3*1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;;1-5(2,3)4/h3*1-8H;;(H2,1,2,3,4)/q;;;+2;/p-2

SMILES string

[Fe++].[O-]S([O-])(=O)=O.c1cnc2c(c1)ccc3cccnc23.c4cnc5c(c4)ccc6cccnc56.c7cnc8c(c7)ccc9cccnc89

InChI key

CIWXFRVOSDNDJZ-UHFFFAOYSA-L

form

liquid

concentration

0.1 wt. % in H2O

density

0.999 g/mL at 25 °C

application(s)

diagnostic assay manufacturing
hematology
histology

storage temp.

room temp

Quality Level

100

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Application

Ferroin indicator solution is suitable for wastewater analysis of the parameters like chemical oxygen demand (COD) and total organic carbon (TOC).

General description

Ferroin serves as an indicator of oxidation reduction reactions in titrimetric analysis. Ferroin is the complex of 1,10-phenanthroline and Fe(II). It is also used as a catalyst for Belousov−Zhabotinsky reaction.

Storage Class

10 - Combustible liquids

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

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Certificates of Analysis (COA)

Lot/Batch Number
SHBS8687
0000491041
0000491041
0000421993
0000311478

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Chemical Demonstrations: A Handbook for Teachers of Chemistry, 2, 261-261 (1985)
Luciano A Cardoso et al.
Comparative biochemistry and physiology. Part A, Molecular & integrative physiology, 151(3), 313-321 (2007-06-05)
Glutathione reductase (GR) carries out the enzymatic reduction of glutathione disulfide (GSSG) to its reduced form (GSH) at the expense of the reducing power of NADPH. Previous studies have shown that GR from several species is progressively inactivated in the
Laszló Hegedüs et al.
The journal of physical chemistry. A, 110(47), 12839-12844 (2006-11-28)
In the present mechanistic schemes of the ferroin-catalyzed oscillatory Belousov-Zhabotinsky (BZ) reaction the oxidation of the organic substrates (bromomalonic or malonic acid) by ferriin (the oxidized form of the catalyst) plays an important role. As the organic products of these
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