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Merck
CN

326208

2-(Diphenylphosphino)benzaldehyde

97%, solid

Synonym(s):

(2-Formylphenyl)diphenylphosphine, o-(Diphenylphosphino)benzaldehyde

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About This Item

Linear Formula:
(C6H5)2PC6H4CHO
CAS Number:
50777-76-9
Molecular Weight:
290.30
UNSPSC Code:
12352114
PubChem Substance ID:
24859571
NACRES:
NA.22
MDL number:
MFCD00013367

Key Documents

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Product Name

2-(Diphenylphosphino)benzaldehyde, 97%

SMILES string

O=Cc1ccccc1P(c2ccccc2)c3ccccc3

InChI

1S/C19H15OP/c20-15-16-9-7-8-14-19(16)21(17-10-3-1-4-11-17)18-12-5-2-6-13-18/h1-15H

InChI key

DRCPJRZHAJMWOU-UHFFFAOYSA-N

assay

97%

form

solid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

mp

112-115 °C (lit.)

functional group

aldehyde
phosphine

Quality Level

100

Related Categories

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCV3668
MKCS2086
MKCN7479
MKCG9539
MKCD3954

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Božidar Čobeljić et al.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry, 21(2), 145-162 (2015-11-28)
Square-planar azido Ni(II) complex with condensation product of 2-(diphenylphosphino)benzaldehyde and Girard's T reagent was synthesized and its crystal structure was determined. Cytotoxic activity of the azido complex and previously synthesized isothiocyanato, cyanato and chlorido Ni(II) complexes with this ligand was

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