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326208

2-(Diphenylphosphino)benzaldehyde

Name: 2-(Diphenylphosphino)benzaldehyde
Brand: ALDRICH

97%, solid

Synonym(s):

(2-Formylphenyl)diphenylphosphine, o-(Diphenylphosphino)benzaldehyde

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About This Item

Linear Formula:

(C₆H₅)₂PC₆H₄CHO

CAS Number:

50777-76-9

Molecular Weight:

290.30

UNSPSC Code:

12352114

PubChem Substance ID:

24859571

NACRES:

NA.22

MDL number:

MFCD00013367

Assay:

97%

Form:

solid

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Properties

Product Name

2-(Diphenylphosphino)benzaldehyde, 97%

Quality Level

100

assay

97%

form

solid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand

mp

112-115 °C (lit.)

functional group

aldehyde, phosphine

SMILES string

O=Cc1ccccc1P(c2ccccc2)c3ccccc3

InChI

1S/C19H15OP/c20-15-16-9-7-8-14-19(16)21(17-10-3-1-4-11-17)18-12-5-2-6-13-18/h1-15H

InChI key

DRCPJRZHAJMWOU-UHFFFAOYSA-N

Description

pictograms

GHS07

signalword

Warning

hcodes

H315,H319,H335

pcodes

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Investigation of antitumor potential of Ni(II) complexes with tridentate PNO acylhydrazones of 2-(diphenylphosphino)benzaldehyde and monodentate pseudohalides.

Božidar Čobeljić et al.

Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry, 21(2), 145-162 (2015-11-28)

Square-planar azido Ni(II) complex with condensation product of 2-(diphenylphosphino)benzaldehyde and Girard's T reagent was synthesized and its crystal structure was determined. Cytotoxic activity of the azido complex and previously synthesized isothiocyanato, cyanato and chlorido Ni(II) complexes with this ligand was

Global Trade Item Number

SKU	GTIN
326208-1G	04061826716076