327131
(S)-(+)-1-Iodo-2-methylbutane
contains copper as stabilizer, 99%
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About This Item
Linear Formula:
C2H5CH(CH3)CH2I
CAS Number:
Molecular Weight:
198.05
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352101
MDL number:
Assay:
99%
Form:
liquid
InChI
1S/C5H11I/c1-3-5(2)4-6/h5H,3-4H2,1-2H3/t5-/m0/s1
SMILES string
CC[C@H](C)CI
InChI key
RHBHXHXNWHTGSO-YFKPBYRVSA-N
assay
99%
form
liquid
optical activity
[α]20/D +5.7°, neat
contains
copper as stabilizer
refractive index
n20/D 1.497 (lit.)
bp
148 °C (lit.)
density
1.525 g/mL at 25 °C (lit.)
functional group
alkyl halide, iodo
Application
(S)-(+)-1-Iodo-2-methylbutane may be used in the synthesis of 4′-trimethylenebis(1-methyl-1-(2-methylbutyl)piperidinium) cation (TMBP2+), to be used as a structure-directing agent (SDA) during the synthesis of high-silica porous silicates. It may also be used in the synthesis of C6 acyl side chain of zaragozic acid A.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
109.4 °F - closed cup
flash_point_c
43 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Regulatory Information
危险化学品
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Total synthesis of zaragozic acid A (squalestatin S1). Degradation to a relay compound and reassembly of the natural product.
Stoermer D, et al.
The Journal of Organic Chemistry, 61(26), 9115-9125 (1996)
Organic-silicate hybrid catalysts based on various defined structures for Knoevenagel condensation.
Kubota Y, et al.
Microporous and Mesoporous Materials : The Official Journal of the International Zeolite Association, 70(1), 135-149 (2004)
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