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Merck
CN

327697

Tris[2-(diphenylphosphino)ethyl]phosphine

greener alternative

97%

Synonym(s):

Tetraphos-Li

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About This Item

Linear Formula:
[(C6H5)2PCH2CH2]3P
CAS Number:
Molecular Weight:
670.68
UNSPSC Code:
12352002
NACRES:
NA.22
PubChem Substance ID:
EC Number:
245-754-3
MDL number:
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InChI key

TVLNGWSWPKIYAO-UHFFFAOYSA-N

InChI

1S/C42H42P4/c1-7-19-37(20-8-1)44(38-21-9-2-10-22-38)34-31-43(32-35-45(39-23-11-3-12-24-39)40-25-13-4-14-26-40)33-36-46(41-27-15-5-16-28-41)42-29-17-6-18-30-42/h1-30H,31-36H2

SMILES string

C(CP(c1ccccc1)c2ccccc2)P(CCP(c3ccccc3)c4ccccc4)CCP(c5ccccc5)c6ccccc6

assay

97%

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

134-135 °C (lit.)

functional group

phosphine

greener alternative category

Quality Level

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Ligand used in iron-catalyzed, greener reduction of aldehydes to alcohols under transfer hydrogenation conditions.

Fast and selective iron-catalyzed transfer hydrogenations of aldehydes

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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