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327956

(1R)-(+)-Nopinone

98%

Synonym(s):

6,6-Dimethylbicyclo[3.1.1]heptan-2-one

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About This Item

Empirical Formula (Hill Notation):
C9H14O
CAS Number:
Molecular Weight:
138.21
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352115
MDL number:
Assay:
98%
Form:
liquid
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Quality Segment

assay

98%

form

liquid

optical activity

[α]20/D +16°, neat

refractive index

n20/D 1.479 (lit.)

bp

209 °C (lit.)

density

0.981 g/mL at 25 °C (lit.)

functional group

ketone

storage temp.

2-8°C

SMILES string

CC1(C)[C@H]2CCC(=O)[C@@H]1C2

InChI

1S/C9H14O/c1-9(2)6-3-4-8(10)7(9)5-6/h6-7H,3-5H2,1-2H3/t6-,7-/m0/s1

InChI key

XZFDKWMYCUEKSS-BQBZGAKWSA-N

Application

(1R)-(+)-Nopinone may be used in the preparation of a chiral annulated indene derivative, which can be a potentially useful chiral ligand for transition metal complexes in asymmetric transformations. It may also react with secondary amines in cyclohexane to form the corresponding enamines.


Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

167.0 °F - closed cup

flash_point_c

75 °C - closed cup

ppe

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)



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