328219
[1,2-Bis(diphenylphosphino)ethane]dichloronickel(II)
solid
Synonym(s):
1,2-Ethylenebis(diphenylphosphine)nickel dichloride, Nickel 1,2-Bis(diphenylphosphino)ethane dichloride, [1,2-Bis(diphenylphosphino)ethane]nickel(II) chloride, dppeNiCl2
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About This Item
Product Name
[1,2-Bis(diphenylphosphino)ethane]dichloronickel(II),
SMILES string
Cl[Ni]Cl.C(CP(c1ccccc1)c2ccccc2)P(c3ccccc3)c4ccccc4
InChI
1S/C26H24P2.2ClH.Ni/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2
InChI key
XXECWTBMGGXMKP-UHFFFAOYSA-L
form
solid
reaction suitability
core: nickel
reagent type: catalyst
mp
263-265 °C (lit.)
Quality Level
Related Categories
Application
- Kumada catalyst-transfer polycondensation
- Oxidation of carboranyl phosphine ligands
- Synthesis of nickel-iron dithiolato hydrides
- Ullmann reactions - homocoupling reactions
Co-catalyst for hydroformylation of alcohols for the synthesis of quaternary carbon centers
Catalyst for Wacker-type intramolecular aerobic oxidative amination of alkenes
signalword
Danger
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 1B - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
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Articles
Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.
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