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331074

(4R)-4-(2-Hydroxyethyl)-2,2-dimethyl-1,3-dioxolane

Name: (4<I>R</I>)-4-(2-Hydroxyethyl)-2,2-dimethyl-1,3-dioxolane
Brand: ALDRICH

96%

Synonym(s):

2-[(4R)-2,2-Dimethyl-1,3-dioxolan-4-yl]ethanol

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About This Item

Empirical Formula (Hill Notation):

C₇H₁₄O₃

CAS Number:

70005-89-9

Molecular Weight:

146.18

NACRES:

NA.22

PubChem Substance ID:

24859931

UNSPSC Code:

12352005

MDL number:

MFCD02682966

Assay:

96%

Form:

liquid

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Properties

Quality Level

100

assay

96%

form

liquid

refractive index

n20/D 1.4390 (lit.)

bp

207 °C (lit.)

density

1.045 g/mL at 25 °C (lit.)

functional group

ether, hydroxyl, ketal

SMILES string

CC1(C)OC[C@@H](CCO)O1

InChI

1S/C7H14O3/c1-7(2)9-5-6(10-7)3-4-8/h6,8H,3-5H2,1-2H3/t6-/m1/s1

InChI key

YYEZYENJAMOWHW-ZCFIWIBFSA-N

Description

Application

(4R)-4-(2-Hydroxyethyl)-2,2-dimethyl-1,3-dioxolane can be used:

To introduce a chiral center selectively in the carbon chain C10 during the total synthesis of protectin D1.
As a starting material in the total synthesis of an anti-diabetic molecule cytopiloyne.
As a starting material in the preparation of 4-¹⁵N-amino-2-butane-1,2-diol, which is used to synthesize ¹⁵N-labeled oligodeoxynucleotides.

pictograms

GHS07

signalword

Warning

hcodes

H315,H319,H335

pcodes

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

222.8 °F - closed cup

flash_point_c

106 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

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Total synthesis of the potent anti-inflammatory lipid mediator Protectin D1

Rodriguez AR and Spur BW

Tetrahedron Letters, 55(43), 6011-6015 (2014)

Total synthesis of the potent anti-inflammatory lipid mediator Protectin D1.

Rodriguez AR and Spur BW.