331597
2-Methoxythiophene
97%
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About This Item
Empirical Formula (Hill Notation):
C5H6OS
CAS Number:
Molecular Weight:
114.17
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
240-863-2
MDL number:
Assay:
97%
Form:
liquid
InChI key
OKEHURCMYKPVFW-UHFFFAOYSA-N
InChI
1S/C5H6OS/c1-6-5-3-2-4-7-5/h2-4H,1H3
SMILES string
COc1cccs1
assay
97%
form
liquid
refractive index
n20/D 1.528 (lit.)
bp
151-152 °C/762 mmHg (lit.)
density
1.133 g/mL at 25 °C (lit.)
Quality Level
Related Categories
General description
2-Methoxythiophene is a heterocyclic methyl enol ether and its reaction with o-quinone monoimide was studied. The intramolecular and intermolecular geometries of crystals of 2-methoxythiophene were investigated. Kinetics of the hydronium-ion catalysed hydrolysis of 2-methoxythiophene was reported.
Application
2-Methoxythiophene was used in thermal reaction (60°C) of (C5Me5)Rh(PMe3)(Ph)H.
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Reversible carbon protonation in the hydrolysis of heterocyclic enol methyl ethers.
Capon B and Kwok F-C.
Tetrahedron, 43(1), 69-76 (1987)
Reactions of an o-quinone monoimide with 1, 3, 5-trimethoxybenzene, 2-methoxythiophene, 2-methoxyfuran, and 1-methyl-, 2-methyl-, and 1, 2-dimethylindoles.
Heine HW, et al.
The Journal of Organic Chemistry, 52(1), 97-101 (1987)
Blake et al.
Acta crystallographica. Section B, Structural science, 55(Pt 6), 963-974 (2000-08-06)
The intramolecular and intermolecular geometries of six thiophenes carrying oxygen-containing substituents have been determined. Crystals of 2-methoxythiophene and 3-methoxythiophene were grown in situ on a diffractometer from liquid samples. The 2-methoxy group introduces significant distortions to the thiophene nucleus and
Bond cleavage reactions in substituted thiophenes by a rhodium complex.
Myers AW, et al.
Inorgorganica Chimica Acta, 361(11), 3263-3270 (2008)
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