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331880

(1S,2R)-(+)-2-Amino-1,2-diphenylethanol

Name: (1<I>S</I>,2<I>R</I>)-(+)-2-Amino-1,2-diphenylethanol
Brand: ALDRICH

99%

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About This Item

Linear Formula:

C₆H₅CH(NH₂)CH(C₆H₅)OH

CAS Number:

23364-44-5

Molecular Weight:

213.28

UNSPSC Code:

12352116

NACRES:

NA.22

PubChem Substance ID:

24860005

MDL number:

MFCD00074959

Beilstein/REAXYS Number:

1212828

Assay:

99%

Form:

solid

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Properties

Quality Level

100

assay

99%

form

solid

optical activity

[α]25/D +7.0°, c = 0.6 in ethanol

mp

142-144 °C (lit.)

functional group

amine, hydroxyl, phenyl

SMILES string

N[C@@H]([C@@H](O)c1ccccc1)c2ccccc2

InChI

1S/C14H15NO/c15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12/h1-10,13-14,16H,15H2/t13-,14+/m1/s1

InChI key

GEJJWYZZKKKSEV-KGLIPLIRSA-N

Description

Application

(1S,2R)-(+)-2-Amino-1,2-diphenylethanol can be used:

To prepare vanadium(V) Schiff base complexes, which are used as catalysts in the oxidation of sulfides and olefins.
To prepare chiral selectors, which are immobilized on aminated silica gel, applicable as chiral stationary phase in HPLC.
To immobilize on the frame of α-zirconium phosphate to yield layered zirconium phosphonates, which are used in the heterogeneous catalysis.
As a chiral auxiliary in the preparation of homopropargylic alcohols from aliphatic and aromatic aldehydes.

pictograms

GHS07

signalword

Warning

hcodes

H315,H319,H335

pcodes

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Vanadium (V) complexes with chiral tridentate Schiff base ligands derived from 1S, 2R (+)-2-amino-1, 2-diphenylethanol and with acetohydroxamate co-ligand: Synthesis, characterization and catalytic activity in the oxidation of prochiral sulfides and olefins

Romanowski G, et al.

J. Mol. Catal. A: Chem., 381, 148-160 (2014)

Zirconium phosphonate immobilized chiral amino alcohol for heterogeneous enantioselective addition of diethylzinc to benzaldehyde

Zheng B, et al.

Catalysis Communications, 8(12), 1923-1928 (2007)

Asymmetric indium-mediated synthesis of homopropargylic alcohols

Hirayama LC, et al.

Tetrahedron Letters, 47(29), 5173-5176 (2006)

View All Related Papers

Global Trade Item Number

SKU	GTIN
331880-1G	04061826249147
331880-5G	04061833037942