333344
Tripropyl orthoformate
97%
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About This Item
Linear Formula:
CH(OCH2CH2CH3)3
CAS Number:
Molecular Weight:
190.28
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
210-704-1
Beilstein/REAXYS Number:
1744249
MDL number:
Assay:
97%
InChI key
RWNXXQFJBALKAX-UHFFFAOYSA-N
InChI
1S/C10H22O3/c1-4-7-11-10(12-8-5-2)13-9-6-3/h10H,4-9H2,1-3H3
SMILES string
CCCOC(OCCC)OCCC
assay
97%
Quality Level
bp
106-108 °C/40 mmHg (lit.)
density
0.883 g/mL at 25 °C (lit.)
functional group
ether
Related Categories
General description
Gas phase reactions of the rare earth metal cations with tripropyl orthoformate were studied by Fourier transform ion cyclotron resonance mass spectrometry.
Application
Tripropyl orthoformate was used as alcohol donor to investigate the activity and enantioselectivity of Novozym 435 in the esterification of rac-fenoprofen in methylcyclohexane. It may be used as a drying agent during the synthesis of squaraine derivatives.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
10 - Combustible liquids
wgk
WGK 1
flash_point_f
161.6 °F - closed cup
flash_point_c
72 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Regulatory Information
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Gas phase reactivity of rare earth metal cations with trialkylorthoformates: synthesis of neutral rare earth alkoxides.
Marchande N, et al
International Journal of Mass Spectrometry, 195, 139-148 (2000)
Convenient preparation of (s)-fenoprofen by biocatalysed irreversible esterification.
Morrone R, et al.
Rasayan Journal of Chemistry, 1, 732-737 (2008)
Advances in synthesis and application of near-infrared absorbing squaraine dyes.
Hu L, et al.
Royal Society of Chemistry Advances, 3(21), 7667-7676 (2013)
Synthesis of squaraine dyes under mild conditions: applications for labelling and sensing of biomolecules.
Sleiman MH and Ladame S.
Chemical Communications (Cambridge, England), 50(40), 5288-5290 (2014)
The structure/property relationship in a series of pyrrolic polysquaraines.
Lynch DE and Ewington J.
Synt. Metals, 183, 40-49 (2013)
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