333557
(1-Bromovinyl)trimethylsilane
97%
Synonym(s):
α-(Trimethylsilyl)vinyl bromide
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About This Item
Linear Formula:
H2C=C(Br)Si(CH3)3
CAS Number:
Molecular Weight:
179.13
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
237-195-9
Beilstein/REAXYS Number:
1742258
MDL number:
Assay:
97%
Form:
liquid
InChI key
VVDJVCJVVHHCIB-UHFFFAOYSA-N
InChI
1S/C5H11BrSi/c1-5(6)7(2,3)4/h1H2,2-4H3
SMILES string
C[Si](C)(C)C(Br)=C
vapor density
>1 (vs air)
assay
97%
form
liquid
refractive index
n20/D 1.458 (lit.)
bp
124 °C/745 mmHg (lit.)
density
1.156 g/mL at 25 °C (lit.)
functional group
bromo
storage temp.
2-8°C
Quality Level
General description
Tetrakis(triphenylphosphine)palladium(0) catalyzed coupling reactions of (1-bromovinyl)trimethylsilane with organozinc bromides were studied.
signalword
Danger
hcodes
pcodes
Hazard Classifications
Flam. Liq. 2
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
55.4 °F - closed cup
flash_point_c
13 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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Abnormal products of palladium catalysed coupling reactions of (1-bromovinyl) trimethylsilane.
Ennis DS and Gilchrist TL.
Tetrahedron Letters, 30(28), 3735-3736 (1989)
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