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333557

(1-Bromovinyl)trimethylsilane

Name: (1-Bromovinyl)trimethylsilane
Brand: ALDRICH

97%

Synonym(s):

α-(Trimethylsilyl)vinyl bromide

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About This Item

Linear Formula:

H₂C=C(Br)Si(CH₃)₃

CAS Number:

13683-41-5

Molecular Weight:

179.13

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24860146

EC Number:

237-195-9

Beilstein/REAXYS Number:

1742258

MDL number:

MFCD00014927

Assay:

97%

Form:

liquid

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Properties

vapor density

>1 (vs air)

Quality Level

100

assay

97%

form

liquid

refractive index

n20/D 1.458 (lit.)

bp

124 °C/745 mmHg (lit.)

density

1.156 g/mL at 25 °C (lit.)

functional group

bromo

storage temp.

2-8°C

SMILES string

C[Si](C)(C)C(Br)=C

InChI

1S/C5H11BrSi/c1-5(6)7(2,3)4/h1H2,2-4H3

InChI key

VVDJVCJVVHHCIB-UHFFFAOYSA-N

Description

General description

Tetrakis(triphenylphosphine)palladium(0) catalyzed coupling reactions of (1-bromovinyl)trimethylsilane with organozinc bromides were studied.

pictograms

GHS02

signalword

Danger

hcodes

H225

pcodes

P210

Hazard Classifications

Flam. Liq. 2

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

55.4 °F - closed cup

flash_point_c

13 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

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Abnormal products of palladium catalysed coupling reactions of (1-bromovinyl) trimethylsilane.

Ennis DS and Gilchrist TL.

Tetrahedron Letters, 30(28), 3735-3736 (1989)

Global Trade Item Number

SKU	GTIN
333557-5G	04061837072680
333557-1G	04061837072673