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333670

Tris(trimethylsilyl)phosphine

95%, liquid

Synonym(s):

(P(TMS)3), Tris(trimethylsilyl)phosphane

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About This Item

Linear Formula:
[(CH3)3Si]3P
CAS Number:
15573-38-3
Molecular Weight:
250.54
UNSPSC Code:
12161700
PubChem Substance ID:
24860167
NACRES:
NA.22
MDL number:
MFCD00015487
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Product Name

Tris(trimethylsilyl)phosphine, 95%

Quality Segment

100

assay

95%

form

liquid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand

refractive index

n20/D 1.502 (lit.)

bp

243-244 °C (lit.)

density

0.863 g/mL at 25 °C (lit.)

functional group

phosphine

storage temp.

2-8°C

SMILES string

C[Si](C)(C)P([Si](C)(C)C)[Si](C)(C)C

InChI

1S/C9H27PSi3/c1-11(2,3)10(12(4,5)6)13(7,8)9/h1-9H3

InChI key

OUMZKMRZMVDEOF-UHFFFAOYSA-N

Application

Tris(trimethylsilyl)phosphine (P(TMS)3) can be used as a precursor for the syntheses of:
  • Indium phosphide (InP) and indium gallium phosphide (InGaP) nanocrystals, type III-V semiconductors.
  • Chiral TMS-phospholane which can be further used to synthesize various bisphospholane ligands for asymmetric catalysis.

pictograms

FlameExclamation mark
GHS02,GHS07

signalword

Danger

target_organs

Respiratory system

Storage Class

4.2 - Pyrophoric and self-heating hazardous materials

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Hazard Classifications

Eye Irrit. 2 - Pyr. Liq. 1 - Skin Irrit. 2 - STOT SE 3 - Water-react. 3

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