334995
Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II)
Synonym(s):
Carbonylchlorohydrotris(triphenylphosphine)ruthenium
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About This Item
Linear Formula:
[(C6H5)3P]3Ru(CO)(Cl)H
CAS Number:
Molecular Weight:
952.40
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
241-051-0
MDL number:
Quality Level
reaction suitability
core: ruthenium, reagent type: catalyst
mp
204-206 °C (dec.) (lit.)
SMILES string
Cl[Ru].[C-]#[O+].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9
InChI
1S/3C18H15P.CO.ClH.Ru/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;;/h3*1-15H;;1H;/q;;;;;+1/p-1
InChI key
MVJRXTSUBHUUPN-UHFFFAOYSA-M
General description
Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II) is a coordination compound commonly used as a catalyst in organic synthesis reactions such as hydrogenation, transfer hydrogenative C-C bond-forming reactions, transfer hydrogenation, and α-alkylation of ketones with primary alcohols. In addition, it is used as a precursor of pincer ruthenium carbonyl catalysts for hydrogenation.
Application
- Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II): This ruthenium complex is used as a versatile catalyst for various reactions including hydrogenation, transfer hydrogenation, C-C bond-forming reactions, α-alkylation of ketones with primary alcohols, and as a precursor for pincer ruthenium carbonyl catalysts for hydrogenation. The complex is noted for its physical properties, such as decomposing above its melting point (204-206°C), and its solubility characteristics. It is very insoluble in water, ethanol, and DMSO, sparingly soluble in benzene and acetone, and slightly soluble in chloroform (Kuriyama, 2001).
signalword
Warning
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Carbonylchlorohydridotris (triphenylphosphine) ruthenium (II)
Kuriyama W
Encyclopedia of Reagents for Organic Synthesis, Second Edition, 1-7 (2001)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 334995-1G | 04061826738719 |
| 334995-5G | 04061833498972 |