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Merck
CN

335363

[1,3-Bis(diphenylphosphino)propane]dichloronickel(II)

powder

Synonym(s):

(1,3-dppp)NiCl2, 1,3-Bis(diphenylphosphino)propane nickel(II) chloride, Ni(dppp)Cl2

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About This Item

Linear Formula:
[(C6H5)2P(CH2)3P(C6H5)2]NiCl2
CAS Number:
15629-92-2
Molecular Weight:
542.04
UNSPSC Code:
12161600
PubChem Substance ID:
24860309
NACRES:
NA.22
MDL number:
MFCD00015318

Key Documents

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Product Name

[1,3-Bis(diphenylphosphino)propane]dichloronickel(II),

SMILES string

Cl[Ni]Cl.C(CP(c1ccccc1)c2ccccc2)CP(c3ccccc3)c4ccccc4

InChI

1S/C27H26P2.2ClH.Ni/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27;;;/h1-12,14-21H,13,22-23H2;2*1H;/q;;;+2/p-2

InChI key

ZBQUMMFUJLOTQC-UHFFFAOYSA-L

form

powder

reaction suitability

core: nickel, reaction type: Cross Couplings, reagent type: catalyst

mp

213 °C (dec.) (lit.)

Quality Level

100

Related Categories

Application

Catalyst for:
  • Synthesis of block-copolythiophenes
  • Suzuki-Miyaura cross-coupling reaction of aryl halides with arylboronic acids
  • Solid state metathesis polycondensation
  • Polymerization of poly(3-alkoxythiophene)s
  • Diastereoselective Nozaki-Hiyama-Kishi coupling reactions of C1-C19 fragment of macrolide antibiotic aplyronine A
  • Transfer condensation polymerization of conjugated polymers
[1,3-Bis(diphenylphosphino)propane]dichloronickel(II) can be used as a precursor to synthesize metal-fullerene coordination complexes by reduction method.

pictograms

Health hazardExclamation mark
GHS08,GHS07

signalword

Danger

Hazard Classifications

Carc. 1A - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
MKCT5778
MKCN8457
0000094470
MKCL7329
0000071214

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The ?2 Complex of Nickel Bis (diphenylphosphanyl) propane with Fullerene
Konarev DV, et al.
European Journal of Inorganic Chemistry, 2011(6), 816-820 (2011)
Renxuan Xie et al.
Nature communications, 11(1), 893-893 (2020-02-16)
The glass transition temperature (Tg) is a key property that dictates the applicability of conjugated polymers. The Tg demarks the transition into a brittle glassy state, making its accurate prediction for conjugated polymers crucial for the design of soft, stretchable
Verónica Fernández-Stefanuto et al.
Frontiers in chemistry, 8, 208-208 (2020-04-09)
Surfactants have a great number of applications. Among these chemicals, petroleum sulfonates have been widely used due to their effectiveness in reducing interfacial tension. This is the case of sodium octylnaphthalene sulfonate which is a solid with a very low
Xiaoyu Li et al.
Nature communications, 8, 15909-15909 (2017-06-27)
Micelles formed by the self-assembly of block copolymers in selective solvents have attracted widespread attention and have uses in a wide variety of fields, whereas applications based on their electronic properties are virtually unexplored. Herein we describe studies of solution-processable
Kinga Kepska et al.
Chemicke zvesti, 72(1), 251-259 (2018-01-26)
The first comprehensive spectroelectrochemical account of the behaviour of regioregular (RR-P3HT) and statistical (ST-P3HT) poly(3-hexylthiophenes) in solution is presented, in contrast to the many reports dealing with P3HT films merely deposited from solution. The conducted experiments revealed that the two
View All Related Papers

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