335363
[1,3-Bis(diphenylphosphino)propane]dichloronickel(II)
powder
Synonym(s):
(1,3-dppp)NiCl2, 1,3-Bis(diphenylphosphino)propane nickel(II) chloride, Ni(dppp)Cl2
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About This Item
Product Name
[1,3-Bis(diphenylphosphino)propane]dichloronickel(II),
form
powder
Quality Segment
reaction suitability
core: nickel, reaction type: Cross Couplings, reagent type: catalyst
mp
213 °C (dec.) (lit.)
SMILES string
Cl[Ni]Cl.C(CP(c1ccccc1)c2ccccc2)CP(c3ccccc3)c4ccccc4
InChI
1S/C27H26P2.2ClH.Ni/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27;;;/h1-12,14-21H,13,22-23H2;2*1H;/q;;;+2/p-2
InChI key
ZBQUMMFUJLOTQC-UHFFFAOYSA-L
Application
- Synthesis of block-copolythiophenes
- Suzuki-Miyaura cross-coupling reaction of aryl halides with arylboronic acids
- Solid state metathesis polycondensation
- Polymerization of poly(3-alkoxythiophene)s
- Diastereoselective Nozaki-Hiyama-Kishi coupling reactions of C1-C19 fragment of macrolide antibiotic aplyronine A
- Transfer condensation polymerization of conjugated polymers
signalword
Danger
Hazard Classifications
Carc. 1A - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3
target_organs
Respiratory system
Storage Class
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
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