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336874

Allyldiphenylphosphine

95%, liquid

Synonym(s):

Diphenyl-2-propenylphosphine, NSC 180819, NSC 616248

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About This Item

Linear Formula:
(C6H5)2PCH2CH=CH2
CAS Number:
2741-38-0
Molecular Weight:
226.25
UNSPSC Code:
12352002
PubChem Substance ID:
24860435
NACRES:
NA.22
MDL number:
MFCD00014954
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Product Name

Allyldiphenylphosphine, 95%

Quality Segment

assay

95%

form

liquid

reaction suitability

reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand, reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction

refractive index

n20/D 1.619 (lit.)

bp

194-200 °C/15 mmHg (lit.)

density

1.049 g/mL at 25 °C (lit.)

functional group

phosphine

SMILES string

C=CCP(c1ccccc1)c2ccccc2

InChI

1S/C15H15P/c1-2-13-16(14-9-5-3-6-10-14)15-11-7-4-8-12-15/h2-12H,1,13H2

InChI key

PDDYFPPQDKRJTK-UHFFFAOYSA-N

Application

  • Cocatalyst in palladium catalyzed hydrocarboxylation reactions
  • Cocatalyst in Palladium catalyzed cross-coupling reactions
  • Ligand for hydroformylation catalysts
  • Ligand for the rhenium phosphinoborane pendant Lewis acid-assisted reductive coupling reactions
  • Catalyst precursor for alkene hydroboration

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Codes

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class

10 - Combustible liquids

WGK

WGK 3

Flash Point (°F)

235.4 °F - closed cup

Flash Point (°C)

113 °C - closed cup

PPE (personal protective equipment)

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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