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Merck
CN

336904

Ethyldiphenylphosphine

98%, liquid

Synonym(s):

Diphenylethylphosphine, NSC 151254

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About This Item

Linear Formula:
(C6H5)2PCH2CH3
CAS Number:
Molecular Weight:
214.24
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352002
MDL number:
Beilstein/REAXYS Number:
744253
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Product Name

Ethyldiphenylphosphine, 98%

Quality Segment

assay

98%

form

liquid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand

refractive index

n20/D 1.614 (lit.)

bp

293 °C (lit.)

density

1.048 g/mL at 25 °C (lit.)

functional group

phosphine

SMILES string

CCP(c1ccccc1)c2ccccc2

InChI

1S/C14H15P/c1-2-15(13-9-5-3-6-10-13)14-11-7-4-8-12-14/h3-12H,2H2,1H3

InChI key

WUOIAOOSKMHJOV-UHFFFAOYSA-N

Application

Catalyst for:
  • Three component coupling reactions of arylaldehydes with Me vinyl ketone and phthalimide
  • Regio- and stereoselective hydroalkynylation of methylenecyclopropanes
  • Synthesis of oxazolidines, thiazolidines, pyrrolidines, and indoles
  • Dimer to monomer conversion
  • Tandem Morita-Baylis-Hillman/Michael addition reactions
  • Platinum-catalyzed cyclization
  • Regioselective and stereoselective [3+2] cycloaddition
  • Platinum-catalyzed intermolecular hydroamination
  • Hydroformylation reactions


pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

230.0 °F - closed cup

flash_point_c

110 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter



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