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336947

Tribenzylphosphine

98%

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About This Item

Linear Formula:
(C6H5CH2)3P
CAS Number:
7650-89-7
Molecular Weight:
304.37
EC Number:
231-608-6
UNSPSC Code:
12352002
PubChem Substance ID:
24860443
Beilstein/REAXYS Number:
650179
MDL number:
MFCD00014439
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assay

98%

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand

mp

96-101 °C (lit.)

functional group

phosphine

SMILES string

C(P(Cc1ccccc1)Cc2ccccc2)c3ccccc3

InChI

1S/C21H21P/c1-4-10-19(11-5-1)16-22(17-20-12-6-2-7-13-20)18-21-14-8-3-9-15-21/h1-15H,16-18H2

InChI key

IFXORIIYQORRMJ-UHFFFAOYSA-N

Application

Cocatalyst in:
  • Preparation of coumarin derivatives via nickel-catalyzed cycloaddition
  • Copolymerization reactions
  • Rh-catalyzed hydroformylation reactions
  • Platinum-catalyzed oxidative hydroxylation reactions
  • Preparation of substituted allylamines by three-component coupling of alkynes, imines and organoboranes
  • Ruthenium catalyzed metathesis reactions (Degenerate ligand exchange)

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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