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Merck
CN

337331

Dichloro(1,5-cyclooctadiene)ruthenium(II), polymer

greener alternative

95%

Synonym(s):

(1,5-Cyclooctadiene)ruthenium(II) chloride, Ruthenium(II) chloride 1,5-cyclooctadiene complex

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About This Item

Linear Formula:
[Ru(COD)Cl2]n
CAS Number:
Molecular Weight:
280.16 (as monomer)
MDL number:
UNSPSC Code:
12161600
NACRES:
NA.22
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Assay

95%

reaction suitability

core: ruthenium
reaction type: solution phase peptide synthesis
reagent type: catalyst

greener alternative product characteristics

Catalysis
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SMILES string

[Ru+2].[Cl-].[Cl-].C1CC=CCCC=C1

InChI

1S/C8H12.2ClH.Ru/c1-2-4-6-8-7-5-3-1;;;/h1-2,7-8H,3-6H2;2*1H;/q;;;+2/p-2

InChI key

DMRVBCXRFYZCPR-UHFFFAOYSA-L

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Versatile Ru catalyst precursor. Used with IMes to catalyze the dehydrogenative coupling of alcohols and amines to form amide bonds.
Versatile ruthenium catalyst precursor. Used with NHC ligand to catalyze greener amide bond formation by dehydrogenative coupling of amines and alcohols.

Amide Synthesis from Alcohols and Amines by the Extrusion of Dihydrogen

Pictograms

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Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Articles

We are proud to offer a number of products used in catalytic amidation technology.

Protocols

Acetylene chemistry's versatile applications from organic synthesis to bioorganic chemistry demand efficient synthesis methods.

乙炔化学一直是并且仍然是分子科学的重要组成部分。它的潜力和广泛的应用从有机合成到材料科学再到生物有机化学。一些例子是烯二炔(DNA切割剂),“点击化学”工具和构建块。 因此,它引发了对高效合成炔烃的需求。

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