33737
Dibenzyl N,N-dimethylphosphoramidite
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About This Item
Empirical Formula (Hill Notation):
C16H20NO2P
CAS Number:
Molecular Weight:
289.31
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
7427974
InChI
1S/C16H20NO2P/c1-17(2)20(18-13-15-9-5-3-6-10-15)19-14-16-11-7-4-8-12-16/h3-12H,13-14H2,1-2H3
SMILES string
CN(C)P(OCc1ccccc1)OCc2ccccc2
InChI key
GDEJGFHRPXLQNN-UHFFFAOYSA-N
refractive index
n20/D 1.553
density
1.089 g/mL at 20 °C (lit.)
functional group
amine, phenyl
storage temp.
2-8°C
Quality Level
Related Categories
Application
Dibenzyl N,N-dimethylphosphoramidite was used in the preparation of dibenzyl phosphoramidates incorporating the representative C-terminal protected amino acids leucine, phenylalanine, glutamic acid and proline. It was also used for the fast and clean phosphitylation of alcohols, including hindered alcohols.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Regulatory Information
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Synthesis of N-phosphoryl amino acids via phosphoramidite amine-exchange.
Chow CP and Berkman CE.
Tetrahedron Letters, 39(41), 7471-7474 (1998)
M. Schneider et al.
Ger. Offen. 4'329'533 (1993)
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