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Merck
CN

337439

Tri-O-benzyl-D-glucal

97%

Synonym(s):

(3R,4S,5R)-3,4,6-Tri-O-benzyl-D-glucal, 1,5-Anhydro-2-deoxy-3,4,6-tris-O-(phenylmethyl)-D-arabino-hex-1-enitol, 3,4,6-Tri-O-benzyl-D-glucal, Tri-OBn-glucal

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About This Item

Empirical Formula (Hill Notation):
C27H28O4
CAS Number:
55628-54-1
Molecular Weight:
416.51
Beilstein:
1691968
MDL number:
MFCD00061640
UNSPSC Code:
12352201
PubChem Substance ID:
24860481
NACRES:
NA.22

Key Documents

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Assay

97%

optical activity

[α]25/D −2.7°, c = 5 in chloroform

mp

57-58 °C (lit.)

storage temp.

−20°C

SMILES string

C(OCc1ccccc1)[C@H]2OC=C[C@@H](OCc3ccccc3)[C@@H]2OCc4ccccc4

InChI

1S/C27H28O4/c1-4-10-22(11-5-1)18-28-21-26-27(31-20-24-14-8-3-9-15-24)25(16-17-29-26)30-19-23-12-6-2-7-13-23/h1-17,25-27H,18-21H2/t25-,26-,27+/m1/s1

InChI key

MXYLLYBWXIUMIT-PFBJBMPXSA-N

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Application

Important building block for both solution- and solid-phase synthesis of oligosaccharides.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCL7000
BCCG0046
BCBZ8667
BCBD8687V
BCBN1211V

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Seeberger, P.H., et al.
Aldrichimica Acta, 30, 75-75 (1997)

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