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337773

Chlorodiisopropylphosphine

96%, liquid

Sustainability features

Synonym(s):

Diisopropylphosphine chloride

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About This Item

Linear Formula:
[(CH3)2CH]2PCl
CAS Number:
40244-90-4
Molecular Weight:
152.60
UNSPSC Code:
12352001
PubChem Substance ID:
24860498
NACRES:
NA.22
MDL number:
MFCD00015027
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Product Name

Chlorodiisopropylphosphine, 96%

Quality Segment

assay

96%

form

liquid

reaction suitability

reagent type: ligand
reaction type: Arylations

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Sustainability features

refractive index

n20/D 1.475 (lit.)

bp

69 °C/33 mmHg (lit.)

density

0.959 g/mL at 25 °C (lit.)

functional group

phosphine

greener alternative category

SMILES string

CC(C)P(Cl)C(C)C

InChI

1S/C6H14ClP/c1-5(2)8(7)6(3)4/h5-6H,1-4H3

InChI key

JZPDBTOWHLZQFC-UHFFFAOYSA-N

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of the 12 Principles of Green Chemistry. This intermediate enables synthesis of organophosphine ligands and phosphinites through direct reaction with alcohols and organometallic reagents. It reduces reliance on commercial ligands and enables tailored catalyst development. Click here for more information.

Application

Chlorodiisopropylphosphine can be used:
  • To synthesize p-styryldiisopropylphosphine by reacting with 4-chlorostyrene via Grignard reaction.
  • As a phosphination reagent in combination with [Cp2Zr(1-butene)(DMAP)] (Cp=cyclopentadienyl; DMAP= 4-(dimethylamino)pyridine)) for the zirconophosphination of alkynes to form zirconoalkenylphosphines.
  • A luminescent mixed-donor platinum POCN pincer complex via cyclometalation process.

Pictograms

FlameCorrosion
GHS02,GHS05

Signal Word

Danger

Hazard Codes

H225,H314

Hazard Classifications

Flam. Liq. 2 - Skin Corr. 1B

Storage Class

3 - Flammable liquids

WGK

WGK 3

Flash Point (°F)

39.2 °F - closed cup

Flash Point (°C)

4 °C - closed cup

PPE (personal protective equipment)

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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