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337773

Chlorodiisopropylphosphine

Name: Chlorodiisopropylphosphine
Brand: ALDRICH

96%, liquid

Synonym(s):

Diisopropylphosphine chloride

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About This Item

Linear Formula:

[(CH₃)₂CH]₂PCl

CAS Number:

40244-90-4

Molecular Weight:

152.60

UNSPSC Code:

12352001

PubChem Substance ID:

24860498

NACRES:

NA.22

MDL number:

MFCD00015027

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Properties

Product Name

Chlorodiisopropylphosphine, 96%

Quality Segment

100

assay

96%

form

liquid

reaction suitability

reagent type: ligand
reaction type: Arylations

refractive index

n20/D 1.475 (lit.)

bp

69 °C/33 mmHg (lit.)

density

0.959 g/mL at 25 °C (lit.)

functional group

phosphine

SMILES string

CC(C)P(Cl)C(C)C

InChI

1S/C6H14ClP/c1-5(2)8(7)6(3)4/h5-6H,1-4H3

InChI key

JZPDBTOWHLZQFC-UHFFFAOYSA-N

Description

Application

Chlorodiisopropylphosphine can be used:

To synthesize p-styryldiisopropylphosphine by reacting with 4-chlorostyrene via Grignard reaction.
As a phosphination reagent in combination with [Cp2Zr(1-butene)(DMAP)] (Cp=cyclopentadienyl; DMAP= 4-(dimethylamino)pyridine)) for the zirconophosphination of alkynes to form zirconoalkenylphosphines.
A luminescent mixed-donor platinum POCN pincer complex via cyclometalation process.

pictograms

GHS02,GHS05

signalword

Danger

hcodes

H225,H314

pcodes

P210 - P233 - P240 - P280 - P303 + P361 + P353 - P305 + P351 + P338

Hazard Classifications

Flam. Liq. 2 - Skin Corr. 1B

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

39.2 °F - closed cup

flash_point_c

4 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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