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Merck
CN

338648

4′-Hexyl-4-biphenylcarbonitrile

liquid crystal (nematic), 98%

Synonym(s):

4′-n -Hexyl-4-cyanobiphenyl, 4′-Hexyl-4-biphenylcarbonitrile, 4′-Hexyl-4-cyanobiphenyl, 4′-Hexyl[1,1′-biphenyl]-4-carbonitrile, 4-Cyano-4′-n -hexylbiphenyl, 4-Cyano-4′-hexyl-1,1′-biphenyl, 4-Cyano-4′-hexylbiphenyl, 4-Hexyl-4′-cyanobiphenyl, 4-Hexyl-4′-cyanodiphenyl, p -Hexyl-p ′-cyanobiphenyl

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About This Item

Linear Formula:
CH3(CH2)5C6H4C6H4CN
CAS Number:
Molecular Weight:
263.38
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
EC Number:
255-228-5
MDL number:
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Product Name

4′-Hexyl-4-biphenylcarbonitrile, liquid crystal (nematic), 98%

InChI key

VADSDVGLFDVIMG-UHFFFAOYSA-N

InChI

1S/C19H21N/c1-2-3-4-5-6-16-7-11-18(12-8-16)19-13-9-17(15-20)10-14-19/h7-14H,2-6H2,1H3

SMILES string

CCCCCCc1ccc(cc1)-c2ccc(cc2)C#N

assay

98%

form

liquid crystal (nematic)

Application

  • Used in thermoresponsive meso/nanostructured PS-b-PEO block copolymer-dispersed liquid crystal.
  • 4′-hexyl-4-biphenylcarbonitrile, 4′-octyloxy-4-biphenylcarbonitrile and their composite liquid crystals were studied for dielectric properties.
Proposed applications are in the field of
  • thermo- and electro optical devices (e.g. optical shutters, smart windows, optical sensors,memories and flexible display devices),
  • n phase array optics (e.g. as switchable birefringent phase shifters).

General description

4′-Hexyl-4-biphenylcarbonitrile belongs to the class of low molecular weight liquid crystals (LCs). Optical properties of LCs can be controlled thermally. It can be rendered opaque to transparent state by thermal switching. This effect appears on account of birefringence feature of LCs. Low molecular weight LCs show high, and strongly dependence on temperature as well as possesses higher solubility in polymer matrices. It also exhibits a strong dipole moment.

hcodes

Hazard Classifications

Aquatic Chronic 4

Storage Class

10 - Combustible liquids

wgk

WGK 3

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

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Thermoresponsive meso/nanostructured thermosetting materials based on PS-b-PEO block copolymer-dispersed liquid crystal: Curing behavior and morphological variation.
Tercjak A, et al.
Acta Materialia, 56(18), 5112-5122 (2008)
Conductance and Dielectric Anisotropy Properties of 4'-Hexyl-4-biphenylcarbonitrile and 4'-Octyloxy-4-biphenylcarbonitrile Liquid Crystals and Their Composite.
Ozgan S, et al.
Asian Journal of Research in Chemistry, 23(7), 3247-3251 (2011)
Hiroshi Kakiuchida et al.
ACS applied materials & interfaces, 11(21), 19404-19412 (2019-05-08)
A simple nonuniform irradiation method for photopolymerization-induced phase separation (PPIPS) was developed to produce unconventional mesoscale domain structures composed of liquid crystal (LC) and reactive mesogen (RM) phases. The LC/RM phase formations and their molecular orientation ordering through PPIPS were

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