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Merck
CN

338893

Lithium phosphate

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Synonym(s):

Lithiophosphate (Li3 PO4 ), Lithium orthophosphate (Li3 PO4 ), Trilithium monophosphate, Trilithium orthophosphate

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About This Item

Linear Formula:
Li3PO4
CAS Number:
10377-52-3
Molecular Weight:
115.79
NACRES:
NA.23
PubChem Substance ID:
24860586
UNSPSC Code:
12352302
EC Number:
233-823-0
MDL number:
MFCD00016187
Form:
powder

Key Documents

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InChI key

TWQULNDIKKJZPH-UHFFFAOYSA-K

InChI

1S/3Li.H3O4P/c;;;1-5(2,3)4/h;;;(H3,1,2,3,4)/q3*+1;/p-3

SMILES string

[Li+].[Li+].[Li+].[O-]P([O-])([O-])=O

form

powder

reaction suitability

core: lithium

greener alternative product characteristics

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concentration

25-27% NaOH (titration)

application(s)

battery precursors
catalysts
material synthesis precursor

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Quality Level

200

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Application

Lithium phosphate (Li₃PO₄) can be used as a precursor in the synthesis of lithium iron phosphate (LiFePO₄) cathode materials for lithium-ion batteries. It can be used as an electrolyte additive to enhance the performance and stability of lithium-ion batteries. Itcan be employed in the production of specialty glasses, where it improves the thermal and chemical properties of the glass.

General description

Lithium phosphate (Li₃PO₄) is a white-colored powder with stringent quality-checking parameters to support R&D activities. Its primary use lies in battery technology, especially in the production of lithium iron phosphate (LiFePO₄) cathode materials for lithium-ion batteries. Beyond this, it is also employed in research activities in ceramics and glass manufacturing, catalysis, pharmaceuticals, optoelectronics, corrosion inhibition, laboratory reagents etc.

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pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H302

Hazard Classifications

Acute Tox. 4 Oral

Storage Class

11 - Combustible Solids

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCZ6133
MKCX3381
0000312269
MKCW0851
0000312269

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Chemical vapor deposition of lithium phosphate thin-films for 3D all-solid-state Li-ion batteries
Xie J, et al.
Journal of the Electrochemical Society, 162(3), A249-A254 (2015)
A Reyes Jiménez et al.
Nanoscale, 10(4), 2128-2137 (2018-01-13)
In this work, we present a comprehensive study on the influence of lithium phosphorus oxynitride (LIPON) as a possible "artificial SEI layer" on the electrochemical performance of pure silicon (Si) thin film electrodes for a possible application in microbatteries or
Synthesis and characterization of olivine LiNiPO4 for aqueous rechargeable battery
Minakshi M, et al.
Electrochimica Acta, 56(11), 4356-4360 (2011)
Improving rate performance of LiFePO4 cathode materials by hybrid coating of nano-Li3PO4 and carbon
Zhao S, et al.
Journal of alloys and compounds, 566(11), 206-211 (2013)
Angel L Ortiz et al.
Dental materials : official publication of the Academy of Dental Materials, 36(5), 645-659 (2020-04-13)
To elucidate the compositional and microstructural developments of a novel lithium silicate glass-ceramic during its crystallization cycle. Blocks of a lithium silicate glass-ceramic (Obsidian®, Glidewell Laboratories) were cut into 1mm thick plates and polished to 1μm finish. Some of them
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