339768
Tetrakis(acetonitrile)palladium(II) tetrafluoroborate
solid
Synonym(s):
NSC 307191, Palladium(II) tetrafluoroborate tetraacetonitrile complex
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About This Item
Product Name
Tetrakis(acetonitrile)palladium(II) tetrafluoroborate,
form
solid
Quality Segment
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
core: palladium, reagent type: ligand
mp
230 °C (dec.) (lit.)
SMILES string
[Pd++].CC#N.CC#N.CC#N.CC#N.F[B-](F)(F)F.F[B-](F)(F)F
InChI
1S/4C2H3N.2BF4.Pd/c4*1-2-3;2*2-1(3,4)5;/h4*1H3;;;/q;;;;2*-1;+2
InChI key
YWMRPVUMBTVUEX-UHFFFAOYSA-N
General description
Application
Reactant involved in:
- Reactions where it plays a role as the metal source due to weakly coordinated acetonitrile ligands
Precursor for:
- Synthesis of dendritic SCS-pincer palladium complexes
- Palladium complexes of click ligands
- Dipalladium catalysts for use in Heck cross-coupling, Suzuki cross-coupling, and aldehyde olefination
Signal Word
Warning
Hazard Codes
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Inhalation
Storage Class
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
PPE (personal protective equipment)
dust mask type N95 (US), Eyeshields, Gloves
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