Skip to Content
Merck
CN

339822

(S)-α-Methyl-4-nitrobenzylamine hydrochloride

97%

Synonym(s):

(S)-1-(4-Nitrophenyl)ethylamine hydrochloride

Sign In to View Organizational & Contract Pricing.

Select a Size

About This Item

Linear Formula:
O2NC6H4CH(CH3)NH2 · HCl
CAS Number:
132873-57-5
Molecular Weight:
202.64
NACRES:
NA.22
PubChem Substance ID:
24860686
UNSPSC Code:
12352116
MDL number:
MFCD00066312

Key Documents

View All Documentation
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist

Product Name

(S)-α-Methyl-4-nitrobenzylamine hydrochloride, 97%

InChI

1S/C8H10N2O2.ClH/c1-6(9)7-2-4-8(5-3-7)10(11)12;/h2-6H,9H2,1H3;1H/t6-;/m0./s1

SMILES string

Cl.C[C@H](N)c1ccc(cc1)[N+]([O-])=O

InChI key

CZQQGVFHLSBEDV-RGMNGODLSA-N

assay

97%

form

powder

optical activity

[α]25/D −6.5°, c = 1 in 0.05 M NaOH

mp

248-250 °C (lit.)

functional group

amine
nitro

Quality Level

200

Looking for similar products? Visit Product Comparison Guide

Related Categories

Application

(S)-α-Methyl-4-nitrobenzylamine hydrochloride can be used as:
  • A fluorescence-quenching guest in the determination of chiral recognition capabilities of binaphthocrown ether and polythiophene complex.
  • A starting material in the synthesis of chiral cyclopalladated complexes with applications in the resolution of racemic compounds.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

新产品
This item has

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
BCCK5644
BCBR8570V
1451608V
1451608
380675/1

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

The first orthopalladation of a primary nitrobenzylamine. Synthesis of chiral cyclopalladated complexes derived from (S)-α-methyl-4-nitrobenzylamine
Vicente J, et al.
J. Chem. Soc., Dalton Trans., 47(15), 2535-2539 (1995)
Polymer-based supramolecular sensing and application to chiral photochemistry
Fukuhara G
Polymer Journal, 47(10), 649-655 (2015)
Gaku Fukuhara et al.
Chemical communications (Cambridge, England), 48(11), 1641-1643 (2011-12-15)
Chiral recognition abilities of the title host for (R)- and (S)-α-methyl-4-nitrobenzylamine were examined in the ground and excited states to give a relative affinity (K(R)/K(S)) of 2.16 by spectral titration and a relative rate constant (k(R)/k(S)) of 2.23 by fluorescence

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service