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Merck
CN

339830

2-[(Acetoxymethyl)allyl]trimethylsilane

99%

Synonym(s):

2-(Trimethylsilylmethyl)-2-propen-1-yl acetate, 2-(Trimethylsilylmethyl)allyl acetate, 2-Acetoxymethyl-3-(trimethylsilyl)propene

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About This Item

Linear Formula:
CH3CO2CH2C(=CH2)CH2Si(CH3)3
CAS Number:
Molecular Weight:
186.32
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
1933657
Assay:
99%
Form:
liquid
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InChI

1S/C9H18O2Si/c1-8(6-11-9(2)10)7-12(3,4)5/h1,6-7H2,2-5H3

SMILES string

CC(=O)OCC(=C)C[Si](C)(C)C

InChI key

IKQWABMHZKGCLX-UHFFFAOYSA-N

assay

99%

form

liquid

Quality Level

bp

95 °C/7 mmHg (lit.)

density

0.877 g/mL at 25 °C (lit.)

functional group

ester

Application

2-[(Acetoxymethyl)allyl]trimethylsilane was used in the cyclopentane synthesis via Pd(0)-catalyzed reactions with 2π acceptors.

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

159.8 °F - closed cup

flash_point_c

71 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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[3+ 2] Cycloaddition of Trimethylenemethane and its Synthetic Equivalents.
Yamago S and Nakamura E.
Org. React. (2004)

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