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Sigma-Aldrich

Zinc phthalocyanine

Dye content 97 %

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Synonym(s):
Phthalocyanine zinc salt
Empirical Formula (Hill Notation):
C32H16N8Zn
CAS Number:
14320-04-8
Molecular Weight:
577.91
Beilstein:
4121852
EC Number:
238-262-5
MDL number:
MFCD00041955
PubChem Substance ID:
24860701

composition

Dye content, 97%

Quality Level

100

reaction suitability

reagent type: catalyst
core: zinc

λmax

701 nm

Orbital energy

HOMO 5.17 eV (CV)
LUMO 3.78 eV (CV)

OPV Device Performance

ITO/ZnPc:P60 (1:1)/Bphen/Ag

  • Short-circuit current density (Jsc): 11.7 mA/cm2
  • Open-circuit voltage (Voc): 0.54 V
  • Fill Factor (FF): 0.62
  • Power Conversion Efficiency (PCE): 3.9 %

SMILES string

[Zn]1n2c3nc4nc(nc5n1c(nc6nc(nc2c7ccccc37)c8ccccc68)c9ccccc59)c%10ccccc4%10

InChI

1S/C32H16N8.Zn/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25;/h1-16H;/q-2;+2

InChI key

PODBBOVVOGJETB-UHFFFAOYSA-N

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General description

Zinc (II) phthalocyanine (ZnPc) complexes show photosensitizing properties. Phthalocyanines show significant Π−Π interactions and easy formation of H aggregates.

Application

Zinc phthalocyanine finds general applications in industry (catalysts, photoconductors etc) and biomedical (photodynamic therapy, PDT). ZnPc may be used to photooxidise cyclohexane. A study reports functionalization of polymer membrane with ZnPc.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Junseok Lee et al.
Chemical communications (Cambridge, England), 49(15), 1545-1547 (2013-01-18)
A photoresponsive drug releasing system based on mesoporous silica nanoparticles (MSN) was developed. A model drug was decorated on the surfaces via singlet oxygen sensitive linkers and a singlet oxygen-generating photosensitizer was loaded in the mesopores of the MSN. An
Zinc phthalocyanine photocatalyzed oxidation of cyclohexene.
Sehlotho N and Nyokong T
J. Mol. Catal. A: Chem., 219(2), 201-207 (2004)
Sean Marrache et al.
Integrative biology : quantitative biosciences from nano to macro, 5(1), 215-223 (2012-07-27)
A therapeutic technology that combines the phototoxic and immune-stimulating ability of photodynamic therapy (PDT) with the widespread effectiveness of the immune system can be very promising to treat metastatic breast cancer. We speculated that the knowledge of molecular mechanisms of
Jiangtao Ren et al.
Biosensors & bioelectronics, 35(1), 401-406 (2012-04-10)
In this work, a simple and label-free fluorescent method via fluorescent indicator displacement (FID) was proposed for enantioselectively determining d-enantiomer of arginine vasopressin (DV) using DV-specific DNA aptamer (V-apt) and one guanidiniophthalocyanine dye (Zn-DIGP). Zn-DIGP that preferentially binds to single-stranded
Thandekile P Mthethwa et al.
Dalton transactions (Cambridge, England : 2003), 42(14), 4922-4930 (2013-02-07)
A novel thiol functionalized zinc phthalocyanine complex (ZnPcSH) is reported in this work. This complex was conjugated to gold nanoparticles. The photophysical and photochemical properties of the complex and the conjugate were investigated. Upon conjugation a blue shift was observed
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