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345237

[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)

Name: [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)
Brand: ALDRICH

98%, powder

Synonym(s):

PdCl₂(dppe)

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About This Item

Linear Formula:

[(C₆H₅)₂PCH₂CH₂P(C₆H₅)₂]PdCl₂

CAS Number:

19978-61-1

Molecular Weight:

575.74

UNSPSC Code:

12161600

PubChem Substance ID:

24861302

NACRES:

NA.22

MDL number:

MFCD00015702

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Properties

Product Name

[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II), 98%

Quality Level

100

assay

98%

form

powder

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
core: palladium

SMILES string

Cl[Pd]Cl.C(CP(c1ccccc1)c2ccccc2)P(c3ccccc3)c4ccccc4

InChI

1S/C26H24P2.2ClH.Pd/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2

InChI key

LDJXFZUGZASGIW-UHFFFAOYSA-L

Description

pictograms

GHS07

signalword

Warning

hcodes

H315,H319,H335

pcodes

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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The cytotoxicity and mechanism of action of new multinuclear Scaffold AuIII, PdII pincer complexes containing a bis(diphenylphosphino) ferrocene/non-ferrocene ligand.

Leila Tabrizi et al.

Dalton transactions (Cambridge, England : 2003), 46(41), 14164-14173 (2017-10-07)

New multinuclear gold(iii), palladium(ii) pincer complexes containing bis(diphenylphosphino) ferrocene/non-ferrocene ligands of formula [(L)Au(μ2-η2-CS3)Pd(dppf)](PF6)2, 1, and [(L)Au(μ2-η2-CS3)Pd(dppe)](PF6)2, 2 (HL = 5-methoxy-1,3-bis (1-methyl-1H-benzo[d]imidazol-2-yl)benzene, dppf = 1,1'-bis(diphenylphosphino)ferrocene, and dppe = bis(diphenylphosphino)ethane) have been synthesized and fully characterized. Both complexes are more cytotoxic to

Global Trade Item Number

SKU	GTIN
345237-1G	04061826662533