346802
(S)-(−)-Indoline-2-carboxylic acid
99%
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About This Item
Empirical Formula (Hill Notation):
C9H9NO2
CAS Number:
Molecular Weight:
163.17
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
EC Number:
410-860-2
MDL number:
InChI key
QNRXNRGSOJZINA-QMMMGPOBSA-N
InChI
1S/C9H9NO2/c11-9(12)8-5-6-3-1-2-4-7(6)10-8/h1-4,8,10H,5H2,(H,11,12)/t8-/m0/s1
SMILES string
OC(=O)[C@@H]1Cc2ccccc2N1
assay
99%
form
powder
optical activity
[α]20/D −114°, c = 1 in 1 M HCl
mp
177 °C (dec.) (lit.)
functional group
carboxylic acid
Quality Level
Related Categories
Application
Catalyst for enantioselective cyclopropanations.
signalword
Warning
hcodes
Hazard Classifications
Repr. 2 - Skin Sens. 1 - STOT RE 2
Storage Class
11 - Combustible Solids
wgk
WGK 2
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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Roxanne K Kunz et al.
Journal of the American Chemical Society, 127(10), 3240-3241 (2005-03-10)
A new method for enantioselective organocatalytic cyclopropanation is described. This study outlines the identification of a new class of iminium catalyst based on the concept of directed electrostatic activation (DEA). This novel organocatalytic mechanism exploits dual activation of ylide and
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