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347191

Diethyl meso-2,5-dibromoadipate

Name: Diethyl <I>meso</I>-2,5-dibromoadipate
Brand: ALDRICH

98%

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About This Item

Linear Formula:

[-CH₂CH(Br)CO₂C₂H₅]₂

CAS Number:

869-10-3

Molecular Weight:

360.04

NACRES:

NA.22

PubChem Substance ID:

24861319

UNSPSC Code:

12352100

MDL number:

MFCD00075379

Assay:

98%

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Properties

Quality Segment

100

assay

98%

mp

65-67 °C (lit.)

functional group

bromo, ester

SMILES string

CCOC(=O)[C@@H](Br)CC[C@@H](Br)C(=O)OCC

InChI

1S/C10H16Br2O4/c1-3-15-9(13)7(11)5-6-8(12)10(14)16-4-2/h7-8H,3-6H2,1-2H3/t7-,8+

InChI key

UBCNJHBDCUBIPB-OCAPTIKFSA-N

Description

General description

Diethyl meso-2,5-dibromoadipate reacts with N-methylallylamine in the presence of potassium carbonate to yield two diastereomers of diethyl 2-allyl-N-methylpyrrolidine-2,5-dicarboxylate.

Application

Diethyl meso-2,5-dibromoadipate may be employed as difunctional initiator during n-butyl acrylate (n-BuA) polymerization, leading to α,ω-bromo-poly(n-BuA) having narrow molecular weight distribution. It was also used:

as bifunctional atom transfer radical polymerization (ATRP) initiator
as initiator during the solution polymerization of octadecyl ester ether dimer by ATRP
in the synthesis of diethyl 2,5-diazidoadipate

pictograms

GHS05,GHS07

signalword

Danger

hcodes

H314,H335

pcodes

P260 - P271 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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