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347957

Glycine tert-butyl ester hydrochloride

Name: Glycine <I>tert</I>-butyl ester hydrochloride
Brand: ALDRICH

97%, for peptide synthesis

Synonym(s):

tert-Butyl aminoacetate hydrochloride

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About This Item

Linear Formula:

H₂NCH₂CO₂C(CH₃)₃· HCl

CAS Number:

27532-96-3

Molecular Weight:

167.63

UNSPSC Code:

12352209

eCl@ss:

32160406

PubChem Substance ID:

24861538

NACRES:

NA.22

Beilstein/REAXYS Number:

3989048

MDL number:

MFCD00058255

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Properties

Product Name

Glycine tert-butyl ester hydrochloride, 97%

assay

97%

form

powder

reaction suitability

reaction type: solution phase peptide synthesis

mp

141-143 °C (lit.)

application(s)

peptide synthesis

SMILES string

Cl.CC(C)(C)OC(=O)CN

InChI

1S/C6H13NO2.ClH/c1-6(2,3)9-5(8)4-7;/h4,7H2,1-3H3;1H

InChI key

OSWULUXZFOQIRU-UHFFFAOYSA-N

Description

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Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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The amplification of the anticonvulsant effect of vinyl GABA (4-aminohexenoic acid) by esters of glycine.

S Sarhan et al.

Arzneimittel-Forschung, 34(6), 687-690 (1984-01-01)

The synergistic amplification of the anticonvulsant effects of direct and indirect GABA agonists by glycine has previously been demonstrated. We show in the present report that the anticonvulsant effect of vinyl GABA, a GABA-T (4-aminobutyrate: 2-oxoglutarate aminotransferase) inhibitor with antiepileptic

Cinchona alkaloid-based polymer-bound phase-transfer catalysts: efficient enantioselective alkylation of benzophenone imine of glycine esters.

Baptiste Thierry et al.

Molecular diversity, 9(4), 277-290 (2005-11-29)

Cross-linked polystyrene-bound and poly(ethylene glycol)-bound phase-transfer catalysts as well as homopolymers of cinchona alkaloid derivatives have been synthesised. Both soluble and insoluble polymers have been investigated. The enantioselective alkylation of N-diphenyl methylene glycine t-butyl ester has been successfully carried out

A powerful synergistic effect for highly efficient diastereo- and enantioselective phase-transfer catalyzed conjugate additions.

Ming-Qing Hua et al.

Chemical communications (Cambridge, England), 47(5), 1631-1633 (2010-12-01)

An efficient, catalytic, diastereo- and enantioselective conjugate addition of N-(diphenylmethylene)glycine tert-butyl ester to β-aryl substituted enones was realized in the presence of 1 mol% of newly desired dinuclear N-spiro-ammonium salts, affording functionalized α-amino acid derivatives in 57-98% yields with high

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Global Trade Item Number

SKU	GTIN
347957-1G	04061826705421
347957-5G	04061833313831