357537
Pentamethylcyclopentadienyliridium(III) chloride,dimer
96%, solid
Synonym(s):
di-μ-chlorodichlorobis[(1,2,3,4,5-η)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-iridium
Sign In to View Organizational & Contract Pricing.
Select a Size
Change View
About This Item
Empirical Formula (Hill Notation):
C20H30Cl4Ir2
CAS Number:
Molecular Weight:
796.70
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
Product Name
Pentamethylcyclopentadienyliridium(III) chloride,dimer, 96%
Quality Level
assay
96%
form
solid
reaction suitability
core: iridium, reagent type: catalyst
greener alternative product characteristics
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
greener alternative category
SMILES string
Cl[Ir]Cl.Cl[Ir]Cl.C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]2[C](C)[C](C)[C](C)[C]2C
InChI
1S/2C10H15.4ClH.2Ir/c2*1-6-7(2)9(4)10(5)8(6)3;;;;;;/h2*1-5H3;4*1H;;/q;;;;;;2*+2/p-4
InChI key
JDOHSXHCQARCAW-UHFFFAOYSA-J
General description
Pentamethylcyclopentadienyliridium(III) chloride, dimer is utilized as a catalyst in cross-coupling and dimerization reactions.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.
Application
Catalyst for greener amine synthesis from amines and alcohols by hydrogen-borrowing. Precursor to cooperative metal-Bronsted acid catalyst for greener reductive amination using hydrogen gas.
Metal-Brønsted Acid Cooperative Catalysis for Asymmetric Reductive Amination
Development of GSK's reagent guides – embedding sustainability into reagent selection
Metal-Brønsted Acid Cooperative Catalysis for Asymmetric Reductive Amination
Development of GSK's reagent guides – embedding sustainability into reagent selection
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Choose from one of the most recent versions:
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
Total Synthesis of Calothrixins A and B by Palladium-Catalyzed Tandem Cyclization/Cross-Coupling Reaction of Indolylborate
T Abe, et al.
European Journal of Organic Chemistry, 2012, 5018-5027 (2012)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 357537-500MG | 04061831812527 |
| 357537-100MG | 04061831812510 |