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Merck
CN

357715

2-Ethylpyrrole

technical grade, 90%

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About This Item

Empirical Formula (Hill Notation):
C6H9N
CAS Number:
1551-06-0
Molecular Weight:
95.14
NACRES:
NA.22
PubChem Substance ID:
24861936
UNSPSC Code:
12352100
MDL number:
MFCD00060477
Assay:
90%
Form:
liquid

Key Documents

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Product Name

2-Ethylpyrrole, technical grade, 90%

InChI

1S/C6H9N/c1-2-6-4-3-5-7-6/h3-5,7H,2H2,1H3

SMILES string

CCc1ccc[nH]1

InChI key

XRPDDDRNQJNHLQ-UHFFFAOYSA-N

grade

technical grade

assay

90%

form

liquid

refractive index

n20/D 1.497 (lit.)

bp

164-165 °C/754 mmHg (lit.)

density

0.929 g/mL at 25 °C (lit.)

storage temp.

2-8°C

Quality Level

100

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Application

2-Ethylpyrrole may be used in the preparation of 1-(3-methoxyphenyl)-2-ethylpyrrole.

General description

2-Ethylpyrrole is a monosubstituted alkyl pyrrole. Stochastic, Rothemund-type condensation of pyrrole, 2-ethylpyrrole and arylaldehyde yields 3-ethyl-substituted inverted porphyrin, which readily converts to 3-(1′-hydroxyethyl)- and 3-acetyl-inverted porphyrins. 2-Ethylpyrrole is a conjugated five-membered heterocyclic flavor compound and its photooxidation reactivity was investigated.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

143.6 °F - closed cup

flash_point_c

62 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKCR7597
MKCQ2222
MKCG0337
MKCD7949
MKCD5990

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Application of 2-ethylpyrrole for a direct synthesis of 3-substituted inverted porphyrins.
Schmidt I and Chmielewski PJ.
Tetrahedron Letters, 42(36), 6389-6392 (2001)
Reactivity on photooxidation of selected five-membered heterocyclic flavor compounds.
Chen C-W and Ho C-T.
Journal of Agricultural and Food Chemistry, 44(8), 2078-2080 (1996)
Jon C Antilla et al.
The Journal of organic chemistry, 69(17), 5578-5587 (2004-08-17)
This paper details the copper-catalyzed N-arylation of pi-excessive nitrogen heterocycles. The coupling of either aryl iodides or aryl bromides with common nitrogen heterocycles (pyrroles, pyrazoles, indazoles, imidazoles, and triazoles) was successfully performed in good yield with catalysts derived from diamine

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