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Merck
CN

357715

2-乙基吡咯

technical grade, 90%

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关于此项目

经验公式(希尔记法):
C6H9N
化学文摘社编号:
分子量:
95.14
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
90%
Form:
liquid
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grade

technical grade

Quality Level

assay

90%

form

liquid

refractive index

n20/D 1.497 (lit.)

bp

164-165 °C/754 mmHg (lit.)

density

0.929 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

CCc1ccc[nH]1

InChI

1S/C6H9N/c1-2-6-4-3-5-7-6/h3-5,7H,2H2,1H3

InChI key

XRPDDDRNQJNHLQ-UHFFFAOYSA-N

General description

2-Ethylpyrrole is a monosubstituted alkyl pyrrole. Stochastic, Rothemund-type condensation of pyrrole, 2-ethylpyrrole and arylaldehyde yields 3-ethyl-substituted inverted porphyrin, which readily converts to 3-(1′-hydroxyethyl)- and 3-acetyl-inverted porphyrins. 2-Ethylpyrrole is a conjugated five-membered heterocyclic flavor compound and its photooxidation reactivity was investigated.

Application

2-Ethylpyrrole may be used in the preparation of 1-(3-methoxyphenyl)-2-ethylpyrrole.


pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

143.6 °F - closed cup

flash_point_c

62 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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Application of 2-ethylpyrrole for a direct synthesis of 3-substituted inverted porphyrins.
Schmidt I and Chmielewski PJ.
Tetrahedron Letters, 42(36), 6389-6392 (2001)
Reactivity on photooxidation of selected five-membered heterocyclic flavor compounds.
Chen C-W and Ho C-T.
Journal of Agricultural and Food Chemistry, 44(8), 2078-2080 (1996)
Jon C Antilla et al.
The Journal of organic chemistry, 69(17), 5578-5587 (2004-08-17)
This paper details the copper-catalyzed N-arylation of pi-excessive nitrogen heterocycles. The coupling of either aryl iodides or aryl bromides with common nitrogen heterocycles (pyrroles, pyrazoles, indazoles, imidazoles, and triazoles) was successfully performed in good yield with catalysts derived from diamine



全球贸易项目编号

货号GTIN
357715-1G04061838097774