359483
(Methylthio)acetic acid
99%
Synonym(s):
(Methylmercapto)acetic acid
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About This Item
Linear Formula:
CH3SCH2COOH
CAS Number:
Molecular Weight:
106.14
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
219-483-6
Beilstein/REAXYS Number:
1740201
MDL number:
Assay:
99%
Form:
liquid
assay
99%
form
liquid
InChI key
HGTBAIVLETUVCG-UHFFFAOYSA-N
InChI
1S/C3H6O2S/c1-6-2-3(4)5/h2H2,1H3,(H,4,5)
SMILES string
CSCC(O)=O
bp
130-131 °C/27 mmHg (lit.)
mp
13-14 °C (lit.)
density
1.219 g/mL at 25 °C (lit.)
General description
Formation of complexes of methyl thioacetate and copper(II) has been investigated. (Methylthio)acetic acid is an irreversible inhibitor of sarcosine oxidase and is effective in preventing the complete enzyme inactivation during modification.
Application
(Methylthio)acetic acid may be used in the synthesis of (5S,6S,8S)-8-acetoxy-6-(3,4-methylenedioxyphenyl)-1-[(methylthio)-acetyl]-1-azaspiro[4.4]nonane.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
230.0 °F - closed cup
flash_point_c
110 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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Jason A Berberich et al.
Acta biomaterialia, 1(2), 173-181 (2006-05-17)
The determination of creatinine levels in biological fluids is an increasingly important clinical requirement. Amperometric biosensors have been developed based on a three-enzyme system which converts creatinine to amperometrically measurable hydrogen peroxide. The development of the amperometric creatinine biosensor has
M Ikeda et al.
Chemical & pharmaceutical bulletin, 47(7), 983-987 (1999-08-06)
A formal total synthesis of (-)-cephalotaxine (1) has been achieved. The key step is an intramolecular aldol condensation of the diketone 9, which in turn was obtained in three steps from the azabicyclic compound 6 derived from D-proline according to
(METHYLTHIO) ACETATE AND (TERT BUTYLTHIO) ACETATE COMPLEXES OF COPPER (II).
Sandell A.
Acta Chemica Scandinavica, 25(8), 3172-3172 (1971)
P Trickey et al.
Structure (London, England : 1993), 7(3), 331-345 (1999-06-16)
Monomeric sarcosine oxidases (MSOXs) are among the simplest members of a recently recognized family of eukaryotic and prokaryotic enzymes that catalyze similar oxidative reactions with various secondary or tertiary amino acids and contain covalently bound flavins. Other members of this
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