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Merck
CN

359556

4-Azidoaniline hydrochloride

97%

Synonym(s):

4-Aminophenyl azide hydrochloride

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About This Item

Linear Formula:
N3C6H4NH2 · HCl
CAS Number:
91159-79-4
Molecular Weight:
170.60
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24862089
MDL number:
MFCD00043274
Beilstein/REAXYS Number:
7942921
Assay:
97%

Key Documents

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Product Name

4-Azidoaniline hydrochloride, 97%

InChI

1S/C6H6N4.ClH/c7-5-1-3-6(4-2-5)9-10-8;/h1-4H,7H2;1H

SMILES string

Cl.Nc1ccc(cc1)N=[N+]=[N-]

InChI key

SDYAJRBHPPWHSF-UHFFFAOYSA-N

assay

97%

reaction suitability

reaction type: click chemistry

mp

165 °C (dec.) (lit.)

functional group

azide

Quality Level

200

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Application

4-Azidoaniline hydrochloride is suitable for use in the preparation of photo-reactive polymers, poly(acrylic acid) having encorporated phenylazido groups. It may be used in the preparation of 1-(4-aminophenyl)-1H-[1,2,3]-triazol-4-ylcarbonyl-Phe-Gly-Phe-Gly-OH. It is suitable for use in the synthesis of photo-reactive polysaccharides.

pictograms

FlameSkull and crossbones
GHS02,GHS06

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Sol. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

4.1B - Flammable solid hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
STBH8829
STBG1960V
STBF0875V
STBD9378V
BCBG8985V

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R Barbucci et al.
Biomaterials, 24(6), 915-926 (2002-12-31)
Surface microfabrication techniques were widely utilised for the spatial control of in vitro cell behaviour. A photo-immobilisation procedure was utilised to create micropatterned surfaces: four different stripe patterns (100, 50, 25 and 10 microm) of hyaluronan (Hyal) and its sulphated
Yoshihiro Ito et al.
Biomaterials, 24(18), 3021-3026 (2003-08-05)
A protein micro-array, called a "cell chip" was constructed by using a photo-reactive polymer for a cell-adhesion assay. Various amounts of albumin or fibronectin were covalently immobilized on a polystyrene dish using a micro-spotter with a dip pen. First, poly(acrylic
Y Ito et al.
Journal of biomaterials science. Polymer edition, 12(4), 367-378 (2001-07-05)
Heparin was immobilized on a polystyrene plate in a graded micropattern by photolithography. The micropattern was confirmed by staining with brilliant green. In the presence of basic fibroblast growth factor (bFGF), the growth of NIH3T3 cells was enhanced only in
Elena A Pritchina et al.
Physical chemistry chemical physics : PCCP, 8(6), 719-727 (2006-02-17)
The photochemistry of p-azidoaniline was studied in argon matrices in the absence and presence of oxygen. With the help of quantum chemical calculations we were able to characterize the triplet p-aminophenylnitrene as well as the cis- and trans-p-aminophenylnitroso oxides. It
D R Nisbet et al.
Journal of biomedical materials research. Part A, 89(1), 24-35 (2008-04-12)
In this study, thermoresponsive xyloglucan hydrogel scaffolds were investigated as candidates for neural tissue engineering of the spinal cord. The hydrogels were optimized to provide similar mechanical properties to that of native spinal cord, although also being functionalized through the
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