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Merck
CN

360082

2-Phenylbenzyl bromide

97%

Synonym(s):

2-(Bromomethyl)biphenyl

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About This Item

Linear Formula:
C6H5C6H4CH2Br
CAS Number:
19853-09-9
Molecular Weight:
247.13
NACRES:
NA.22
PubChem Substance ID:
24862143
UNSPSC Code:
12352100
MDL number:
MFCD00075454

Key Documents

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Product Name

2-Phenylbenzyl bromide, 97%

InChI

1S/C13H11Br/c14-10-12-8-4-5-9-13(12)11-6-2-1-3-7-11/h1-9H,10H2

SMILES string

BrCc1ccccc1-c2ccccc2

InChI key

SEXZHJJUKFXNDY-UHFFFAOYSA-N

assay

97%

form

liquid

refractive index

n20/D 1.6280 (lit.)

bp

120-125 °C/0.1 mmHg (lit.)

density

1.353 g/mL at 25 °C (lit.)

functional group

bromo
phenyl

Application

2-Phenylbenzyl bromide may be used in the synthesis of a parent skeleton of 9H-fluorene.

General description

2-Phenylbenzyl bromide is a halogenated hydrocarbon.

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
1437541V
1437541
09121PD
05205KD
19215HO

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Seung Jun Hwang et al.
Organic letters, 11(20), 4588-4591 (2009-09-17)
A facile protocol for the Pd-catalyzed preparative synthesis of fluorene derivatives has been developed. While a wide range of fluorenes were easily obtained with high efficiency and selectivity under mild conditions, excellent functional group tolerance was also demonstrated. On the
Hayrettin O Gülcan et al.
Archiv der Pharmazie, 348(1), 55-61 (2015-01-13)
The current structure-activity relationship of profens (i.e., 2-arylpropionic acid derivatives, a class of non-steroidal anti-inflammatory drugs) discusses the importance of α-monomethyl substitution on these compounds, since the activities obtained through their corresponding arylacetic acid derivatives (i.e., α-demethylated derivatives) or α,α-dimethyl-substituted

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