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Merck
CN

361844

Chlorotris(triphenylphosphine)cobalt(I)

97%, powder

Synonym(s):

CoCl(Ph3P)3

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About This Item

Linear Formula:
[(C6H5)3P]3CoCl
CAS Number:
26305-75-9
Molecular Weight:
881.24
UNSPSC Code:
12161600
PubChem Substance ID:
24862267
NACRES:
NA.22
MDL number:
MFCD00015864

Key Documents

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Product Name

Chlorotris(triphenylphosphine)cobalt(I), 97%

SMILES string

Cl[Co].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9

InChI

1S/3C18H15P.ClH.Co/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h3*1-15H;1H;/q;;;;+1/p-1

InChI key

RHNBOEDTKLKUEB-UHFFFAOYSA-M

assay

97%

form

powder

reaction suitability

core: cobalt
reagent type: catalyst

mp

135-139 °C (dec.) (lit.)

Quality Level

100

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Application

A stoichiometric reducing agent employed in the radical dimerization of halogenated organic molecules.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCS2670
MKCR9231
MKCK0832
MKCD3763
MKBV8255V

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Sharanjeet K Bagal et al.
The Journal of organic chemistry, 69(26), 9100-9108 (2004-12-22)
The biomimetic synthesis of the bisesquiterpene lactones (+/-)-biatractylolide 1 and (+/-)-biepiasterolide 2 via dimerization of the captodative stabilized radical 8 is reported. Atractylon 7 has also been shown to be a possible intermediate during the biosynthesis of biatractylolide 1, biepiasterolide
Concise total synthesis of (-)-calycanthine, (+)-chimonanthine, and (+)-folicanthine.
Mohammad Movassaghi et al.
Angewandte Chemie (International ed. in English), 46(20), 3725-3728 (2007-04-07)

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