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361844

Chlorotris(triphenylphosphine)cobalt(I)

Name: Chlorotris(triphenylphosphine)cobalt(I)
Brand: ALDRICH

97%, powder

Synonym(s):

CoCl(Ph3P)3

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About This Item

Linear Formula:

[(C₆H₅)₃P]₃CoCl

CAS Number:

26305-75-9

Molecular Weight:

881.24

UNSPSC Code:

12161600

PubChem Substance ID:

24862267

NACRES:

NA.22

MDL number:

MFCD00015864

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Properties

Product Name

Chlorotris(triphenylphosphine)cobalt(I), 97%

Quality Level

100

assay

97%

form

powder

reaction suitability

core: cobalt, reagent type: catalyst

mp

135-139 °C (dec.) (lit.)

SMILES string

Cl[Co].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9

InChI

1S/3C18H15P.ClH.Co/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h3*1-15H;1H;/q;;;;+1/p-1

InChI key

RHNBOEDTKLKUEB-UHFFFAOYSA-M

Description

Application

A stoichiometric reducing agent employed in the radical dimerization of halogenated organic molecules.

pictograms

GHS07

signalword

Warning

hcodes

H302 + H312 + H332

pcodes

P261 - P264 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Dimerization of butenolide structures. A biomimetic approach to the dimeric sesquiterpene lactones (+/-)-biatractylolide and (+/-)-biepiasterolide.

Sharanjeet K Bagal et al.

The Journal of organic chemistry, 69(26), 9100-9108 (2004-12-22)

The biomimetic synthesis of the bisesquiterpene lactones (+/-)-biatractylolide 1 and (+/-)-biepiasterolide 2 via dimerization of the captodative stabilized radical 8 is reported. Atractylon 7 has also been shown to be a possible intermediate during the biosynthesis of biatractylolide 1, biepiasterolide

Concise total synthesis of (-)-calycanthine, (+)-chimonanthine, and (+)-folicanthine.

Mohammad Movassaghi et al.

Angewandte Chemie (International ed. in English), 46(20), 3725-3728 (2007-04-07)

Global Trade Item Number

SKU	GTIN
361844-5G	04061833322444