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Merck
CN

363685

Sigma-Aldrich

Silver carbonate on Celite®

extent of labeling: ~50 wt. % loading

Synonym(s):

Fetizon′s reagent

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About This Item

Linear Formula:
Ag2CO3
CAS Number:
Molecular Weight:
275.75
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23
Form:
powder and chunks
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form

powder and chunks

Quality Level

reaction suitability

core: silver

concentration

45-60 wt. % (by KSCN, titration)

extent of labeling

~50 wt. % loading

SMILES string

[Ag]OC(=O)O[Ag]

InChI

1S/CH2O3.2Ag/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2

InChI key

KQTXIZHBFFWWFW-UHFFFAOYSA-L

Application

Employed in the silver ion induced preparation of α-keto acetals and α,α-dialkoxy imines. Catalyzes the generation of stereospecific unsaturated aldehydes from vinylic halides and primary amines.

Legal Information

Celite is a registered trademark of Imerys Minerals California, Inc.

Pictograms

CorrosionEnvironment

Signal Word

Danger

Hazard Statements

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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Synthesis, 427-427 (1994)
Tetrahedron Letters, 31, 6641-6641 (1990)
Sukalyan Bhadra et al.
Journal of the American Chemical Society, 134(24), 9938-9941 (2012-06-12)
Decarboxylative Chan-Evans-Lam-type couplings are presented as a new strategy for the regiospecific construction of diaryl and alkyl aryl ethers starting from easily available aromatic carboxylic acids. They allow converting various aromatic carboxylate salts into the corresponding aryl ethers by reaction
Akira Ito et al.
The Journal of eukaryotic microbiology, 50(1), 34-42 (2003-04-04)
Morphological features of the four morphotypes of the rumen ciliate, Eodinium posterovesiculatum, are described from pyridinated silver carbonate-impregnated specimens. Infraciliary bands are compared with those of Entodinium bursa and Diplodinium dentatum. In Entodinium bursa, the adoral polybrachykinety is "C" shaped
J M Choe et al.
Urology, 55(4), 515-520 (2000-03-29)
To prospectively assess the outcome results of the Gore-Tex antibacterial mesh sling in women with pelvic prolapse and stress incontinence. Between July 1997 and November 1998, 30 women with stress incontinence and vaginal prolapse underwent vaginal reconstruction with the antibacterial

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Oxidation and reduction reactions are some of the most common transformations encountered in organic synthesis

Silver nanomaterials have unique physical, chemical, and optical properties that are currently being leveraged for a wide variety of biological applications.

银纳米材料具有独特的物理、化学以及光学性质,目前正在用于各种的生物应用。

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