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363685

Silver carbonate on Celite®

extent of labeling: ~50 wt. % loading

Synonym(s):

Fetizon′s reagent

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About This Item

Linear Formula:
Ag2CO3
CAS Number:
534-16-7
Molecular Weight:
275.75
NACRES:
NA.23
PubChem Substance ID:
24862209
UNSPSC Code:
12352302
EC Number:
208-590-3
MDL number:
MFCD00003403
Form:
powder and chunks
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form

powder and chunks

Quality Level

100

reaction suitability

core: silver

concentration

45-60 wt. % (by KSCN, titration)

extent of labeling

~50 wt. % loading

SMILES string

[Ag]OC(=O)O[Ag]

InChI

1S/CH2O3.2Ag/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2

InChI key

KQTXIZHBFFWWFW-UHFFFAOYSA-L

Application

Employed in the silver ion induced preparation of α-keto acetals and α,α-dialkoxy imines. Catalyzes the generation of stereospecific unsaturated aldehydes from vinylic halides and primary amines.

Legal Information

Celite is a registered trademark of Imerys Minerals California, Inc.

pictograms

CorrosionEnvironment
GHS05,GHS09

signalword

Danger

hcodes

H318,H410

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1

Storage Class

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
SHBL5135
SHBL2556
SHBL1869
SHBL1873
SHBK4656

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Articles

Oxidizing and Reducing Agents

Oxidation and reduction reactions are some of the most common transformations encountered in organic synthesis

Silver Nanomaterials for Biological Applications

Silver nanomaterials have unique physical, chemical, and optical properties that are currently being leveraged for a wide variety of biological applications.

用于生物学应用的银纳米材料

银纳米材料具有独特的物理、化学以及光学性质，目前正在用于各种的生物应用。

View All Articles
Synthesis, 427-427 (1994)
Tetrahedron Letters, 31, 6641-6641 (1990)
Gregory L Hamilton et al.
Journal of the American Chemical Society, 130(45), 14984-14986 (2008-10-22)
Reactions proceeding through cationic intermediates that lack a Lewis or Brønsted basic site present a challenge for traditional asymmetric catalysis based on chiral metals or organocatalysts. We present an enantioselective ring opening of tetrasubstituted meso-aziridinium ions with alcohol nucleophiles proceeding
View All Related Papers

Global Trade Item Number

SKUGTIN
363685-5G04061833322468
363685-25G04061831825169