Quality Segment
assay
97%
form
liquid
refractive index
n20/D 1.553 (lit.)
bp
113 °C/3 mmHg (lit.)
density
1.455 g/mL at 25 °C (lit.)
functional group
bromo, ester, phenyl
storage temp.
2-8°C
SMILES string
COC(=O)C(Br)c1ccccc1
InChI
1S/C9H9BrO2/c1-12-9(11)8(10)7-5-3-2-4-6-7/h2-6,8H,1H3
InChI key
NHFBYYMNJUMVOT-UHFFFAOYSA-N
General description
Methyl α-bromophenylacetate is an ester. Palladium catalyzed homocoupling reaction of methyl α-bromophenylacetate with 3,5-dimethyl phenyl boronic acid is reported.
Application
Methyl α-bromophenylacetate may be used as initiator during ESR study of atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA) and ethylene glycol dimethacrylate (EGDMA). It may be used as reagent in the homopolymerization of MMA in supercritical carbon dioxide.
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter