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366404

1,1,4,7,10,10-Hexamethyltriethylenetetramine

97%

Synonym(s):

HMTETA

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About This Item

Linear Formula:
[(CH3)2NCH2CH2N(CH3)CH2-]2
CAS Number:
3083-10-1
Molecular Weight:
230.39
NACRES:
NA.22
PubChem Substance ID:
24862651
UNSPSC Code:
12352100
EC Number:
221-382-7
MDL number:
MFCD00025684
Assay:
97%
Form:
liquid
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Quality Level

100

assay

97%

form

liquid

refractive index

n20/D 1.456 (lit.)

bp

130 °C/11 mmHg (lit.)

density

0.847 g/mL at 25 °C (lit.)

functional group

amine

SMILES string

CN(C)CCN(C)CCN(C)CCN(C)C

InChI

1S/C12H30N4/c1-13(2)7-9-15(5)11-12-16(6)10-8-14(3)4/h7-12H2,1-6H3

InChI key

DWFKOMDBEKIATP-UHFFFAOYSA-N

General description

1,1,4,7,10,10-Hexamethyltriethylenetetramine is a polyamines additive, has been reported as an efficient reagent for the problematic Koenigs-Knorr glucuronidation.

Application

1,1,4,7,10,10-Hexamethyltriethylenetetramine may be used as reagent in the synthesis of ideal linear random copolymers containing both vinyl polymer and polyester units in a single polymer chain. 1,1,4,7,10,10-Hexamethyltriethylenetetramine complexed with CuBr constitutes catalytic complex, used in the copolymerization of poly[ε-caprolactone] with N,N-dimethylamino-2-ethyl methacrylate monomers by atom-transfer radical polymerization (ATRP). It may be used as catalyst in the aqueous surface-initiated-ATRP to grow poly(N,N-dimethylacrylamide) (PDMA).

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

215.6 °F - closed cup

flash_point_c

102 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
MKCV3348
MKCR6686
MKCM9494
MKCJ8395
MKCD2394

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Protocols

Concepts and Tools for RAFT Polymerization

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Polymerizing via ATRP

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

Typical Procedures for Polymerizing via RAFT

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

Stefanie L Baker et al.
Nature communications, 10(1), 4718-4718 (2019-10-19)
Almost all commercial proteins are purified using ammonium sulfate precipitation. Protein-polymer conjugates are synthesized from pure starting materials, and the struggle to separate conjugates from polymer, native protein, and from isomers has vexed scientists for decades. We have discovered that
Bryan R Coad et al.
Langmuir : the ACS journal of surfaces and colloids, 23(23), 11791-11803 (2007-10-11)
We report the use of aqueous surface-initiated atom transfer radical polymerization (SI-ATRP) to grow polymer brushes from a "gigaporous" polymeric chromatography support for use as a novel size exclusion chromatography medium. Poly(N,N-dimethylacrylamide) (PDMA) was grown from hydrolyzable surface initiators via
Weihang Ji et al.
Biomacromolecules, 18(8), 2583-2593 (2017-06-29)
Antibacterial polymers are potentially powerful biocides that can destroy bacteria on contact. Debate in the literature has surrounded the mechanism of action of polymeric biocides and the propensity for bacteria to develop resistance to them. There has been particular interest
View All Related Papers

Global Trade Item Number

SKUGTIN
366404-25G04061836832155
366404-5G04061831826104