Key Documents

View All Documentation

369047

(tert-Butoxycarbonylmethyl)triphenylphosphonium bromide

Name: (<I>tert</I>-Butoxycarbonylmethyl)triphenylphosphonium bromide
Brand: ALDRICH

98%

Synonym(s):

NSC 82468

Select a Size

Change View

About This Item

Linear Formula:

(CH₃)₃CO₂CCH₂P(C₆H₅)₃Br

CAS Number:

59159-39-6

Molecular Weight:

459.36

NACRES:

NA.22

PubChem Substance ID:

24862950

UNSPSC Code:

12352108

MDL number:

MFCD00075527

Assay:

98%

Form:

powder

Technical Service

Need help? Our team of experienced scientists is here for you.

Let Us Assist

Properties

Quality Segment

200

assay

98%

form

powder

reaction suitability

reaction type: C-C Bond Formation

mp

178 °C (dec.) (lit.)

functional group

ester, phosphine

SMILES string

[Br-].CC(C)(C)OC(=O)C[P+](c1ccccc1)(c2ccccc2)c3ccccc3

InChI

1S/C24H26O2P.BrH/c1-24(2,3)26-23(25)19-27(20-13-7-4-8-14-20,21-15-9-5-10-16-21)22-17-11-6-12-18-22;/h4-18H,19H2,1-3H3;1H/q+1;/p-1

InChI key

ZGLFRTJDWWKIAK-UHFFFAOYSA-M

Description

Application

Reactant for:

Rhodium-catalyzed asymmetric hydrogenation reactions
Wittig reaction
Wittig methylenation
Preparation of N-(phenylmethyl)-cis-pyrrolidinediacetic acid esters via double aza-Michael addition reaction
Stereoselective preparation of of α-fluoro-α,β-unsaturated esters via deprotonation, followed by fluorination and stereoselective Wittig olefination with aldehydes
Wittig chain extension reactions

hcodes

H315,H319,H335

pictograms

GHS07

signalword

Warning

pcodes

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library