376159
(三甲基硅基)甲基化异腈
97%
别名:
(异氰甲基)三甲基硅烷
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关于此项目
线性分子式:
(CH3)3SiCH2NC
化学文摘社编号:
分子量:
113.23
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3930556
Assay:
97%
Form:
liquid
Quality Segment
assay
97%
form
liquid
refractive index
n20/D 1.416 (lit.)
bp
52-53 °C/35 mmHg (lit.)
density
0.803 g/mL at 25 °C (lit.)
functional group
amine, isonitrile
storage temp.
−20°C
SMILES string
C[Si](C)(C)C[N+]#[C-]
InChI
1S/C5H11NSi/c1-6-5-7(2,3)4/h5H2,2-4H3
InChI key
OLSTVZKPVGMQKB-UHFFFAOYSA-N
General description
Synthesis of (trimethylsilyl)methyl isocyanide and its reaction with protic nucleophiles has been reported. An improved preparation of (trimethylsilyl)methyl isocyanide is reported. Reaction of (trimethylsilyl)methyl isocyanide with (η2-formaldehyde)zirconocene complex is reported to yield insertion products.
Application
(Trimethylsilyl)methyl isocyanide may be used in the preparation of isocyanomethylenetriphenylphosphorane.
Packaging
Bottomless glass bottle. Contents are inside inserted fused cone.
Disclaimer
Supply conditions do not apply to the regions and states of Brazil: North, Northeast, Mato Grosso do Sul, Mato Grosso, and Rio Grande do Sul.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
<59.0 °F - closed cup
flash_point_c
< 15 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter