376345
(1S,3R)-(−)-Camphoric acid
99%
Synonym(s):
(−)-Camphoric acid, (1S,3R)-1,2,2-Trimethyl-1,3-cyclopentanedicarboxylic acid
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About This Item
Empirical Formula (Hill Notation):
C10H16O4
CAS Number:
Molecular Weight:
200.23
UNSPSC Code:
51113400
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
1874674
Assay:
99%
InChI
1S/C10H16O4/c1-9(2)6(7(11)12)4-5-10(9,3)8(13)14/h6H,4-5H2,1-3H3,(H,11,12)(H,13,14)/t6-,10+/m0/s1
SMILES string
CC1(C)[C@@H](CC[C@]1(C)C(O)=O)C(O)=O
InChI key
LSPHULWDVZXLIL-QUBYGPBYSA-N
assay
99%
optical activity
[α]20/D −48°, c = 10 in ethanol
mp
188-190 °C (lit.)
functional group
carboxylic acid
Quality Level
Related Categories
Application
(1S,3R)-(−)-Camphoric acid can be used:
- As an enantiomeric linker in the preparation of chiral surface-anchored metal-organic frameworks (MOFs).
- To prepare porous MOFs having multifunctional properties; used in gas adsorption and separation of racemic alcohols.
- To prepare a cobalt(II) coordination polymer named {Co(phen)(H2O)[C8H14(COO)2]}n·(CH3OH)n , wherein “phen” is 1,10-phenanthroline and C8H14(COOH)2 is [(1S,3R)-camphoric acid.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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Hydrothermal Synthesis and Crystal Structure of One-dimensional Chain Coordination Polymer
Dai-Zhi X, et al.
Chinese Journal of Inorganic Chemistry / Wu Ji Hua Xue Xue Bao, 14(6), 36-36 (2009)
Two Homochiral Bimetallic Metal-Organic Frameworks Composed of a Paramagnetic Metalloligand and Chiral Camphorates: Multifunctional Properties of Sorption, Magnetism, and Enantioselective Separation
Ryu DW, et al.
Crystal Growth & Design, 14(12), 6472-6477 (2014)
Oriented Circular Dichroism Analysis of Chiral Surface-Anchored Metal-Organic Frameworks Grown by Liquid-Phase Epitaxy and upon Loading with Chiral Guest Compounds
Gu Z, et al.
Chemistry?A European Journal , 20(32), 9879-9882 (2014)
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