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376345

(1S,3R)-(−)-Camphoric acid

Name: (1<I>S</I>,3<I>R</I>)-(−)-Camphoric acid
Brand: ALDRICH

99%

Synonym(s):

(−)-Camphoric acid, (1S,3R)-1,2,2-Trimethyl-1,3-cyclopentanedicarboxylic acid

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About This Item

Empirical Formula (Hill Notation):

C₁₀H₁₆O₄

CAS Number:

560-09-8

Molecular Weight:

200.23

UNSPSC Code:

51113400

NACRES:

NA.22

PubChem Substance ID:

24863434

MDL number:

MFCD00064937

Beilstein/REAXYS Number:

1874674

Assay:

99%

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Properties

assay

99%

optical activity

[α]20/D −48°, c = 10 in ethanol

mp

188-190 °C (lit.)

functional group

carboxylic acid

SMILES string

CC1(C)[C@@H](CC[C@]1(C)C(O)=O)C(O)=O

InChI

1S/C10H16O4/c1-9(2)6(7(11)12)4-5-10(9,3)8(13)14/h6H,4-5H2,1-3H3,(H,11,12)(H,13,14)/t6-,10+/m0/s1

InChI key

LSPHULWDVZXLIL-QUBYGPBYSA-N

Description

Application

(1S,3R)-(−)-Camphoric acid can be used:

As an enantiomeric linker in the preparation of chiral surface-anchored metal-organic frameworks (MOFs).
To prepare porous MOFs having multifunctional properties; used in gas adsorption and separation of racemic alcohols.
To prepare a cobalt(II) coordination polymer named {Co(phen)(H₂O)[C₈H₁₄(COO)₂]}_n·(CH₃OH)_n , wherein “phen” is 1,10-phenanthroline and C₈H₁₄(COOH)₂ is [(1S,3R)-camphoric acid.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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