377171
1,2-Epoxyhexane
97%
Synonym(s):
1-Hexene oxide, Butyloxirane
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About This Item
Empirical Formula (Hill Notation):
C6H12O
CAS Number:
Molecular Weight:
100.16
UNSPSC Code:
12162002
NACRES:
NA.23
PubChem Substance ID:
EC Number:
215-864-6
Beilstein/REAXYS Number:
102568
MDL number:
InChI key
WHNBDXQTMPYBAT-UHFFFAOYSA-N
InChI
1S/C6H12O/c1-2-3-4-6-5-7-6/h6H,2-5H2,1H3
SMILES string
CCCCC1CO1
assay
97%
form
liquid
impurities
<3% acetic acid
refractive index
n20/D 1.406 (lit.)
bp
118-120 °C (lit.)
density
0.831 g/mL at 25 °C (lit.)
storage temp.
2-8°C
Quality Level
Related Categories
Application
- Poly (epichlorohydrin-co-1, 2-epoxyhexane)–a promising precursor for an energetic azido polymer for cast-cure: Discusses the synthesis of a copolymer using epichlorohydrin and 1,2-epoxyhexane, aiming to develop an internal plasticizer for energetic applications (TM Klapötke, 2016).
- Synthesis of hierarchically porous zeolite TS-1 with small crystal size and its performance of 1-hexene epoxidation reaction: This study investigates the catalytic performance of 1,2-epoxyhexane in the preparation of intermediates for various chemical industries (M Zhang et al., 2021).
- Bioproduction of Chiral Epoxyalkanes using Styrene Monooxygenase from Rhodococcus sp. ST‐10 (RhSMO): Focuses on the enzymatic production of (S)-1,2-epoxyhexane using a biocatalyst, highlighting its potential in creating chiral epoxyalkanes (H Toda et al., 2014).
- Silica islands regulated external Ti‐site environment of TS‐1 for enhanced performance of 1‐hexene epoxidation: Explores the use of modified TS-1 catalysts to improve the selectivity and performance of 1,2-epoxyhexane in epoxidation reactions (J Yuan et al., 2023).
- Gas-phase Photocatalytic Oxidation of 1-Hexene Using Heterogeneous Semiconductor Materials: Describes the synthesis of 1,2-epoxyhexane through gas-phase photocatalytic oxidation, focusing on the selectivity and efficiency of the process (EA Kamba et al., 2023).
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
59.0 °F - closed cup
flash_point_c
15 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Regulatory Information
危险化学品
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W J Choi et al.
Applied microbiology and biotechnology, 54(5), 641-646 (2000-12-29)
A two-phase membrane bioreactor was developed to continuously produce enantiopure epoxides using the epoxide hydrolase activity of Rhodotorula glutinis. An aqueous/organic cascade, hydrophilic, hollow-fiber membrane bioreactor was used: (1) to carry out large-scale resolution of epoxides, (2) to continuously extract
Ijaz Gul et al.
Journal of biotechnology, 311, 19-24 (2020-02-19)
Halohydrin dehalogenases (HHDHs) are valuable biocatalysts involved in the synthesis of β-substituted alcohols via their nucleophile-mediated ring-opening activity. To use directed evolution to unleash the latent potential of HHDHs for the synthesis of β-substituted alcohols, we report a high-throughput assay
Christopher J Backlund et al.
Acta biomaterialia, 29, 198-205 (2015-10-20)
The effect of nitric oxide (NO)-releasing dendrimer hydrophobicity on Streptococcus mutans killing and biofilm disruption was examined at pH 7.4 and 6.4, the latter relevant to dental caries. Generation 1 (G1) poly(amidoamine) (PAMAM) dendrimers were modified with alkyl epoxides to
Allison C Vander Wall et al.
Environmental science. Processes & impacts, 22(1), 66-83 (2019-11-02)
Secondary organic aerosol (SOA) particles are ubiquitous in air and understanding the mechanism by which they grow is critical for predicting their effects on visibility and climate. The uptake of three organic nitrates into semi-solid SOA particles formed by α-pinene
Thomas Klein et al.
Dalton transactions (Cambridge, England : 2003), 49(28), 9820-9834 (2020-07-08)
Al nanoparticles represent one of the most challenging classes of metal nanoparticles in synthesis and handling due to their high chemical reactivity and their affinity to oxidation. A promising wet chemical preparation route is the catalytic decomposition of alane adducts.
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