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Merck
CN

377384

Tetraamminepalladium(II) nitrate solution

10 wt. % in H2O, liquid

Synonym(s):

Tetraamminedinitratopalladium, Tetraamminepalladium dinitrate

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About This Item

Linear Formula:
Pd(NH3)4(NO3)2
CAS Number:
13601-08-6
Molecular Weight:
298.55
UNSPSC Code:
12161600
PubChem Substance ID:
24863500
NACRES:
NA.22
MDL number:
MFCD00011591

Key Documents

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Product Name

Tetraamminepalladium(II) nitrate solution, 10 wt. % in H2O

SMILES string

N.N.N.N.[Pd++].[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/2NO3.4H3N.Pd/c2*2-1(3)4;;;;;/h;;4*1H3;/q2*-1;;;;;+2

InChI key

WIDMMNCAAAYGKW-UHFFFAOYSA-N

form

liquid

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

concentration

10 wt. % in H2O

refractive index

n20/D 1.348

density

1.04 g/mL at 25 °C

Quality Level

100

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Application

Precursor to heterogeneous platinum catalysts for isomerizing unfunctionalized alkanes.
Used to prepare a Pd/TS-1 catalyst for the in situ generation of H2O2 and subsequent oxidation of propylene to propylene oxide.

pictograms

Flame over circleExclamation mark
GHS03,GHS07

signalword

Danger

Hazard Classifications

Eye Irrit. 2 - Ox. Liq. 2 - Skin Irrit. 2

Storage Class

5.1B - Oxidizing hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKCW7356
MKCR6663
MKCN0534
MKCJ5343
MKCB2640V

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Direct synthesis of propylene oxide with CO2 as the solvent.
Tiberiu Danciu et al.
Angewandte Chemie (International ed. in English), 42(10), 1140-1142 (2003-03-18)
Aramendia, Maria A.; et al.
J. Catal., 209(2), 413-416 (2002)
J P Berry
Journal of submicroscopic cytology, 19(1), 53-56 (1987-01-01)
Palladium salt has been used for some time in experimental therapy protocols; with this in mind, we carried out a study of the effect of tetramine dichloro-palladium (soluble salt) upon kidney cells. Using an electron microprobe, we were able to
J Ma
The Journal of general physiology, 102(6), 1031-1056 (1993-12-01)
The effects of ruthenium red and the related compounds tetraamine palladium (4APd) and tetraamine platinum (4APt) were studied on the ryanodine activated Ca2+ release channel reconstituted in planar bilayers with the immunoaffinity purified ryanodine receptor. Ruthenium red, applied at submicromolar

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