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378712

(1S)-(+)-Menthyl chloroformate

Name: (1<I>S</I>)-(+)-Menthyl chloroformate
Brand: ALDRICH

optical purity ee: 97% (GLC)

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About This Item

Empirical Formula (Hill Notation):

C₁₁H₁₉ClO₂

CAS Number:

7635-54-3

Molecular Weight:

218.72

UNSPSC Code:

12352101

NACRES:

NA.22

PubChem Substance ID:

24863571

MDL number:

MFCD00134483

Beilstein/REAXYS Number:

2414685

Form:

liquid

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Properties

form

liquid

Quality Segment

100

optical activity

[α]20/D +83°, c = 1 in chloroform

optical purity

ee: 97% (GLC)

refractive index

n20/D 1.458 (lit.)

bp

108-109 °C/11 mmHg (lit.)

density

1.031 g/mL at 25 °C (lit.)

functional group

chloro

storage temp.

2-8°C

SMILES string

CC(C)[C@H]1CC[C@H](C)C[C@@H]1OC(Cl)=O

InChI

1S/C11H19ClO2/c1-7(2)9-5-4-8(3)6-10(9)14-11(12)13/h7-10H,4-6H2,1-3H3/t8-,9+,10-/m0/s1

InChI key

KIUPCUCGVCGPPA-AEJSXWLSSA-N

Description

Application

Chiral auxiliary in the asymmetric synthesis of quaternary carbon centers.

pictograms

GHS06,GHS05

signalword

Danger

hcodes

H314,H331

pcodes

P261 - P271 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 3 Inhalation - Skin Corr. 1B

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

158.0 °F - closed cup

flash_point_c

70 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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