379891
高碘酸
99.999% trace metals basis
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关于此项目
经验公式（希尔记法）:
H5IO6
化学文摘社编号:
分子量:
227.94
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352301
EC Number:
233-937-0
MDL number:
Assay:
99.999% trace metals basis
Form:
crystals
Quality Segment
assay
99.999% trace metals basis
form
crystals
reaction suitability
reagent type: oxidant
mp
122 °C (lit.)
solubility
water: soluble
SMILES string
OI(O)(O)(O)(O)=O
InChI
1S/H5IO6/c2-1(3,4,5,6)7/h(H5,2,3,4,5,6,7)
InChI key
TWLXDPFBEPBAQB-UHFFFAOYSA-N
General description
Periodic acid (H5IO6) is an oxoacid of iodine. It is commonly used as an oxidizing agent in organic synthesis for the preparation of useful chemical intermediates. Periodic acid is also used in oxidative cleavage reactions.
Application
Periodic acid can be used as a reagent:
- In the oxidative cleavage of 1,2 diols and epoxides to ketones or aldehydes.
- For the oxidation of alcohols to ketones or aldehydes in the presence of pyridinium chlorochromate as a catalyst.
- For the oxidation of sulfides to sulfones using chromium(VI) oxide catalyst.
- For the oxidation of naphthalenes and anthracene to quinones using chromium(VI) oxide catalyst.
- In the synthesis of polyaniline (Pani) by chemical polymerization.
- N-nitrosation of secondary amines using various heterogeneous catalysts in the presence of Na2NO3.
- In combination with sodium bisulfate for the preparation iodohydrin substituents by the addition of I-OH to alkenes.
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signalword
Danger
hcodes
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Ox. Sol. 1 - Skin Corr. 1B - STOT RE 1 Oral
target_organs
Thyroid
存储类别
5.1A - Strongly oxidizing hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges